Peculiarities of thermal decomposition of metastable lithium cobaltites / Semenova A.S., Kellerman D.G. // Theoretical and Experimental Chemistry. - 2013. - V. 48, l. 6. - P. 371-375.

ISSN:

00405760

Type:

Article

Abstract:

Chemical deintercalation was used to obtain samples of defective lithium cobaltite formed during charging and discharging in chemical power sources. A study was carried out on the processes occurring upon heating of low-temperature and high-temperature modifications of lithium-deficient cobaltites. Thermal analysis and magnetic susceptibility methods were used to show that the decomposition of metastable cobaltites Li1-xCoO2 is accompanied by the separation of cobalt oxide Co3O4 and oxygen, while the major decomposition product is stoichiometric lithium cobaltite. © 2013 Springer Science+Business Media New York.

Author keywords:

chemical power sources; cobaltite; magnetic susceptibility; thermal stability

Index keywords:

нет данных

DOI:

10.1007/s11237-013-9283-0

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84880698760&doi=10.1007%2fs11237-013-9283-0&partnerID=40&md5=de9f0f769e23be483ae09680ee3bc6cc

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Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84880698760&doi=10.1007%2fs11237-013-9283-0&partnerID=40&md5=de9f0f769e23be483ae09680ee3bc6cc
Affiliations	Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ul. Pervomaiskaya, 91, Ekaterinburg, 620990, Russian Federation
Author Keywords	chemical power sources; cobaltite; magnetic susceptibility; thermal stability
References	Tobishima, S.-I., Takei, K., Sakurai, Y., Yamaki, J.-I., (2000) J. Power Sources, 90, p. 188; Jiang, J., Dahn, J.R., (2004) Electrochem. Commun., 6, pp. 39-43; Wu, M.S., Chiang, P.C., Lin, J.C., Jan, Y.S., (2004) Electrochim. Acta, 49, pp. 1803-1812; Antolini, E., Ferretti, M., (1995) J. Solid State Chem., 117, pp. 1-7; Rossen, E., Reimers, J.N., Dahn, J.R., (1993) Solid State Ionics, 62 (1-2), pp. 53-60; Lundblad, A., Bergman, B.A., (1997) Solid State Ionics, 96 (3-4), pp. 173-181; Kellerman, D.G., Galakhov, V.R., Semenova, A.S., (2006) Fiz. Tverdogo Tela, 48 (3), pp. 510-517; Dahn, J.R., Fuller, E.W., Obrovac, M., von Sacken, U., (1994) Solid State Ionics, 69 (3-4), p. 265; Oku, M., (1978) J. Solid State Chem., 23, p. 177; Cossee, P., (1958) J. Inorg. Nucl. Chem., 8, p. 483; Shao-Horn, Y., Hackney, S.A., Kahaian, A.J., Thackeray, M.M., (2002) J. Solid State Chem., 168, pp. 60-68; Lee, K.K., Yoon, W.S., Kim, K.B., (2001) J. Power Sources, 97-98, p. 321; Schilling, O., Dahn, J.R., (1998) J. Electrochem. Soc., 145 (2), p. 569; Wolverton, C., Zunger, A., (1998) J. Electrochem. Soc., 145 (7), p. 2424
Correspondence Address	Semenova, A. S.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ul. Pervomaiskaya, 91, Ekaterinburg, 620990, Russian Federation; email: semenova@ihim.uran.ru
Language of Original Document	English
Abbreviated Source Title	Theor. Exp. Chem.
Source	Scopus