Some aspects of antiferromagnetic ordering in LiMnP 0.85V 0.15O 4: Neutron diffraction and DC-magnetization studies / Kellerman D.G., Chukalkin Y.G., Mukhina N.A., Gorshkov V.S., Semenova A.S., Teplykh A.E. // Journal of Magnetism and Magnetic Materials. - 2012. - V. 324, l. 19. - P. 3181-3188.

ISSN:
03048853
Type:
Article
Abstract:
V-substituted LiMnPO 4 has been synthesized by the solid state reaction route. Combined Rietveld refinement of neutron and X-ray data revealed that all vanadium ions are located in the same positions as the phosphorus ions. The magnetic structure of LiMnP 0.85V 0.15O 4 was found to be the same as that described for undoped antiferromagnetic LiMnPO 4 (T N=34.5 K). DC-magnetization measurements were carried out to study the peculiarities of magnetic ordering in LiMnP 0.85V 0.15O 4. An irreversible behavior of DC magnetization was found at magnetic fields less than ∼2 kOe. It was demonstrated that an increase in the magnitude of the applied field leads to a reduction of the discrepancy between zero-field-cooled and field-cooled processes. These effects were explained by the movement of domain walls and by transition of the system to a monodomain state. The anomaly in the magnetization vs field dependence attributed presumably to the spin-flop transition was observed at ∼40 kOe. The existence of magnetic inhomogeneity in the paramagnetic phase of LiMnP 0.85V 0.15O 4 was proved by the analysis of the χT product. It was concluded that the observed changes in χT are indicative of a competition between ferromagnetic and antiferromagnetic correlations at temperatures slightly exceeding T N. © 2012 Elsevier B.V. All rights reserved.
Author keywords:
Domain structure; LiMnPO 4; Magnetic heterogeneity; Magnetic susceptibility; Neutron diffraction
Index keywords:
Antiferromagnetic orderings; Antiferromagnetics; Applied field; DC magnetization; Domain structure; Ferromagnetic and anti-ferromagnetic; Field dependence; Irreversible behavior; LiMnPO 4;
DOI:
10.1016/j.jmmm.2012.05.037
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Affiliations Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya st., 91, 620990 Ekaterinburg, Russian Federation; Ural Federal University, 620002 Ekaterinburg, Russian Federation; Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, 620990 Ekaterinburg, Russian Federation; Eliont LLC, 620137 Ekaterinburg, Russian Federation
Author Keywords Domain structure; LiMnPO 4; Magnetic heterogeneity; Magnetic susceptibility; Neutron diffraction
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Correspondence Address Kellerman, D.G.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya st., 91, 620990 Ekaterinburg, Russian Federation; email: kellerman@ihim.uran.ru
CODEN JMMMD
Language of Original Document English
Abbreviated Source Title J Magn Magn Mater
Source Scopus