Cobalt oxide catalyst for hydrolysis of sodium borohydride and ammonia borane / Simagina V.I., Komova O.V., Ozerova A.M., Netskina O.V., Odegova G.V., Kellerman D.G., Bulavchenko O.A., Ishchenko A.V. // Applied Catalysis A: General. - 2011. - V. 394, l. 1-2. - P. 86-92.

ISSN:

0926860X

Type:

Article

Abstract:

The catalytic properties of Co3O4 in NaBH4 and NH3BH3 hydrolysis have been studied. Experiments were carried out at 20-40 °C using 0.12 M hydride solution. According to magnetic susceptibility measurements, FTIR, XRD, and TEM studies, Co 3O4 is reduced to the ferromagnetic catalytically active Co2B phase under the action of the NaBH4 hydrolysis reaction medium. A correlation was found between the content of the cobalt boride phase formed in situ and catalyst activity. The reduction of Co 3O4 in NH3BH3 proceeds at slower rate than in NaBH4. The addition to a solution of NH 3BH3 of even a small amount of NaBH4 increases considerably the reduction rate of Co3O4. Using a Co 3O4-based precursor instead of the widely used CoCl 2 leads to the formation of a stable catalytically active phase of cobalt boride. © 2010 Elsevier B.V.

Author keywords:

Ammonia borane; Cobalt boride; Cobalt oxide; Hydrolysis; Sodium borohydride

Index keywords:

Ammonia borane; B phase; Catalytic properties; Cobalt boride; Cobalt oxide; Cobalt oxide catalysts; FTIR; Hydrolysis reaction; In-situ; Magnetic susceptibility measurements; Reduction rate; Sodium bor

DOI:

10.1016/j.apcata.2010.12.028

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-79951669905&doi=10.1016%2fj.apcata.2010.12.028&partnerID=40&md5=67e6ae72c7776e680c55ed591ae54ec3

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-79951669905&doi=10.1016%2fj.apcata.2010.12.028&partnerID=40&md5=67e6ae72c7776e680c55ed591ae54ec3
Affiliations	Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk, 630090, Russian Federation; Institute of Solid State Chemistry, Pervomaiskaya Street 91, Ekaterinburg, 620219, Russian Federation
Author Keywords	Ammonia borane; Cobalt boride; Cobalt oxide; Hydrolysis; Sodium borohydride
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Correspondence Address	Komova, O. V.; Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk, 630090, Russian Federation; email: komova@catalysis.ru
CODEN	ACAGE
Language of Original Document	English
Abbreviated Source Title	Appl Catal A Gen
Source	Scopus