Magnetic properties of intercalated zinc hexacyanoferrate (II) / Denisova T.A., Maksimova L.G., Kellerman D.G., Melkozerova M.A., Zabolotskaya E.V., Mitrofanov V.Ya., Dorogina G.A. // Solid State Phenomena. - 2011. - V. 168-169, l. . - P. 169-172.

ISSN:
10120394
Type:
Conference Paper
Abstract:
The results of magnetic behavior study of nickel ions, which were introduced into Zn2Fe(CN)6·5.5H2O with channel structure, are presented. It was shown that nickel cations replace a part of Zn2+ ions or locate in the channels of lattice via the molecular mechanism sorption. It is shown that the magnetic moments μNi of the sorption products strongly depend on the content of Ni2+ ions. The values of μNi of the samples with Ni/Fe(CN)6=2.26 and 2.86 are great ∼ 3.9 and 4.4 μB respectively and close to the value typical of free Ni2+ ions μ =4.47μB.
Author keywords:
Magnetic properties; Sorption; Zinc hexacyanoferrate (II)
Index keywords:
Behavioral research; Ethanol; Ions; Magnetic moments; Magnetic properties; Sorption; Ions; Magnetic moments; Magnetic properties; Nickel; Sorption; Zinc; Channel structures; Ethanol solutions; Magneti
DOI:
10.4028/www.scientific.net/SSP
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-79951940507&doi=10.4028%2fwww.scientific.net%2fSSP.168-169.169&partnerID=40&md5=744ba6ed3ae5288f23256e82cc9544d0
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-79951940507&doi=10.4028%2fwww.scientific.net%2fSSP.168-169.169&partnerID=40&md5=744ba6ed3ae5288f23256e82cc9544d0
Affiliations Institute of Solid State Chemistry, UB, RAS, Ekaterinburg, 620990, Russian Federation; Institute of Metallurgy, UB, RAS, 620016 Ekaterinburg, Russian Federation
Author Keywords Magnetic properties; Sorption; Zinc hexacyanoferrate (II)
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Correspondence Address Denisova, T. A.; Institute of Solid State Chemistry, UB, RAS, Ekaterinburg, 620990, Russian Federation; email: secretary@ihim.uran.ru
Publisher Trans Tech Publications Ltd
ISBN 9783037850213
CODEN DDBPE
Language of Original Document English
Abbreviated Source Title Diffus Def Data Pt B
Source Scopus