Optical absorption and nuclear magnetic resonance in lithium titanium spinel doped by chromium / Kellerman D.G., Mukhina N.A., Zhuravlev N.A., Valova M.S., Gorshkov V.S. // Physics of the Solid State. - 2010. - V. 52, l. 3. - P. 459-464.

ISSN:
10637834
Type:
Article
Abstract:
The optical absorption and nuclear magnetic resonance spectra of Li4 - xCr3xTi5 - 2xO12 (x = 0, 0.01, 0.02, 0.04) solid solutions have been investigated. It has been found that, in the Li4Ti5O12 spinel, lithium ions migrate from tetrahedral to octahedral positions with increasing temperature. Doping of chromium to the spinel favors an increase in the fraction of tetrahedrally coordinated lithium and hinders diffusion. © Pleiades Publishing, Ltd., 2010.
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Index keywords:
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DOI:
10.1134/S1063783410030030
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Affiliations Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaǐskaya 91, Yekaterinburg 620041, Russian Federation; Eliont LLC, ul. Shefskaya 1 B,, Yekaterinburg 620137, Russian Federation; Postovskiǐ Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. Sof'i Kovalevskoǐ/Akademicheskaya 22/20, Yekaterinburg 620041, Russian Federation
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Correspondence Address Kellerman, D. G.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaǐskaya 91, Yekaterinburg 620041, Russian Federation; email: kellerman@ihim.uran.ru
Language of Original Document English
Abbreviated Source Title Phys. Solid State
Source Scopus