Semiconductor-metal transition in defect lithium cobaltite / Kellerman D.G., Galakhov V.R., Semenova A.S., Blinovskov Ya.N., Leonidova O.N. // Physics of the Solid State. - 2006. - V. 48, l. 3. - P. 548-556.

ISSN:
10637834
Type:
Article
Abstract:
The magnetic susceptibility, electrical conductivity, and x-ray photoelectron and x-ray absorption spectra of defect lithium cobaltites of the general formula Li1 - x CoO2 are investigated. It is found that, for lithium cobaltites with x > 0.25, the magnetic susceptibility increases abruptly and the conductivity type changes at T ∼ 150 K. The assumption is made that the semiconductor-metal transition in defect lithium cobaltite is caused by the increase in the diffusion mobility of lithium ions with an increase in the temperature when there is a correlation between spatial distributions of lithium vacancies and "electron" holes. © Pleiades Publishing, Inc., 2006.
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DOI:
10.1134/S106378340603022X
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Affiliations Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaǐskaya 91, Yekaterinburg, 620219, Russian Federation; Institute of Metal Physics, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoǐ 18, Yekaterinburg, 620219, Russian Federation
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Correspondence Address Kellerman, D.G.; Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaǐskaya 91, Yekaterinburg, 620219, Russian Federation; email: kellerman@ihim.uran.ru
Language of Original Document English
Abbreviated Source Title Phys. Solid State
Source Scopus