Cluster formation in LiNi0.4Fe0.6O2 / Kellerman D.G., Shalaeva E.V., Gusev A.I. // Physics of the Solid State. - 2004. - V. 46, l. 9. - P. 1686-1692.

ISSN:
10637834
Type:
Article
Abstract:
The structure of an LiNi0.4Fe0.6O2 cubic solid solution is determined using magnetic measurements and electron diffraction. It is found that this solid solution has a microinhomogeneous structure due to the formation of superparamagnetic clusters. The electron diffraction analysis of LiNi0.4Fe0.6O2 samples has revealed diffuse scattering characteristic of the substitutional short-range order in ordered solid solutions with a B1-type structure. It is shown that the short-range order is associated with the LiNiO2-type rhombohedral superstructure (space group R3m), i.e., with the redistribution of lithium and nickel atoms in the (111)B1 alternating planes. The short-range order is observed in regions with a nickel content higher than the mean nickel content corresponding to the macroscopic composition. © 2004 MAIK "Nauka/Interperiodica".
Author keywords:
Index keywords:
нет данных
DOI:
10.1134/1.1799188
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-5644300678&doi=10.1134%2f1.1799188&partnerID=40&md5=22a42a91dfb93a1aa9f5bfeddf9dfb49
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Affiliations Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaǐskaya 91, Yekaterinburg, 620219, Russian Federation
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Correspondence Address Kellerman, D.G.; Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaǐskaya 91, Yekaterinburg, 620219, Russian Federation
Language of Original Document English
Abbreviated Source Title Phys. Solid State
Source Scopus