New complex oxides of the A3n+3mA′nB 3m+nO9m+6n family: Ba6A′Mn 4O15 (A′= Mg, Ni) / Bazuev G.V., Zaitseva N.A., Kellerman D.G. // Solid State Sciences. - 2003. - V. 5, l. 11-12. - P. 1465-1470.

ISSN:

12932558

Type:

Article

Abstract:

Complex oxides Ba6AMn4O15, where A = Mg (I) and Ni (II), belonging to the homologous series A3n+3A′ B3m+nO9m+6n (n = 1, m = 1) were obtained by solid state reaction method from Ba carbonate and oxides MgO, NiO, MnO2. Both new oxides are incommensurate. Their crystal structures were interpreted as composite ones with two subcells: a = 10.042(3) Å, c1 = 4.318(2) Å, c2 = 2.565(1) Å, c1/c2 = 1.6834 for (I) and a = 10.044(3) Å, c1 = 4.308(2) Å, c2 = 2.551(1) Å, C1/C2 = 1.6887 for (II). Magnetic susceptibility measurements in the range 2-850 K revealed antiferromagnetic correlations in Ba6MgMn4O15 (TN = 7 K) and a pseudo-square-planar environment of some Ni2+ cations in Ba 6NiMn4O15. © 2003 Elsevier SAS. All rights reserved.

Author keywords:

Crystal structure; Magnetic properties; Synthesis

Index keywords:

Antiferromagnetic materials; Carbonates; Crystal structure; Magnetic susceptibility; Magnetic variables measurement; Manganese compounds; Positive ions; Antiferromagnetic correlation; Solid state reac

DOI:

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0345526929&partnerID=40&md5=cd2b3b213aa58e23044f5ebadc564ec7
Affiliations	Institute of Solid State Chemistry, Ural Br. of the Russ. Acad. of Sci., Ekaterinburg 620219, Russian Federation
Author Keywords	Crystal structure; Magnetic properties; Synthesis
Chemicals/CAS	barium, 7440-39-3; magnesium oxide, 1309-48-4, 1317-74-4; manganese oxide, 11129-60-5, 1317-35-7; manganese, 16397-91-4, 7439-96-5; nickel monoxide, 11099-02-8, 1313-99-1; nickel, 7440-02-0; perovskite, 12194-71-7, 61027-03-0
References	Darriet, J., Subramanian, M.A., (1995) J. Mater. Chem., 5, p. 543; Dussarrat, C., Fompeyrine, J., Darriet, J., (1995) Eur. J. Solid State Inorg. Chem., 32, p. 3; Campa, J.A., Gutierrez, E., Monge, M.A., Rasines, I., Ruiz-Valero, C., (1994) J. Solid State Chem., 108, p. 230; Perez-Mato, J.M., Zakhour-Nakhl, M., Weill, F., Darriet, J., (1999) J. Mater. Chem., 9, p. 2795; Boulahya, K., Parras, M., Gonzalez-Calbet, J.M., (1999) J. Solid State Chem., 145, p. 116; Bazuev, G.V., Zubkov, V.G., Berger, I.F., Arbuzova, T.I., (1999) Solid State Sci., 1, p. 365; Cussen, E.J., Vente, J.F., Battle, P.D., (1999) J. Am. Chem. Soc., 121, p. 3958; Kawasaki, S., Takano, M., Inami, T., (1999) J. Solid State Chem., 145, p. 303; Zubkov, V.G., Bazuev, G.V., Tyutyunnik, A.P., Berger, I.F., (2001) J. Solid State Chem., 160, p. 293; El Abed, A., Gaudin, E., Lemaux, S., Darriet, J., (2001) Solid State Sci., 3, p. 887; Bazuev, G.V., Kellerman, D.G., (2002) Russ. J. Inorg. Chem., 47, p. 1772; Bazuev, G.V., Zaitseva, N.A., Krasilnikov, V.N., Kellerman, D.G., (2003) Russ. J. Inorg. Chem., 48, p. 217; Bazuev, G.V., Krasilnikov, V.N., Kellerman, D.G., (2003) J. Alloys Compd., 352, p. 190; El Abed, A., Gaudin, E., Darriet, J., (2002) Acta Crystallogr. C., Cryst. Struct. Commun., 58 (10), p. 1138; Battle, P.D., Burley, J.C., Cussen, E.J., Darriet, J., Weill, F., (1999) J. Mater. Chem., 9, p. 479; Bazuev, G.V., Zaitseva, N.A., Krasilnikov, V.N., (2002) Russ. J. Inorg. Chem., 47, p. 1418; Battle, P.D., Blake, G.R., Darriet, J., Gore, J.G., Weill, F., (1997) J. Mater. Chem., 7, p. 1559; Whangbo, M., Koo, H.-J., Lee, K.-S., Gourdon, O., Evain, M., Jobic, S., Brec, R., (2001) J. Solid State Chem., 160, p. 239; Vajenine, G.V., Hoffmann, R., Zur Loye, H.-C., (1996) Chem. Phys., 204, p. 469
Correspondence Address	Bazuev, G.V.; Institute of Solid State Chemistry, Ural Br. of the Russ. Acad. of Sci., Ekaterinburg 620219, Russian Federation; email: bazuev@ihim.uran.ru
CODEN	SSSCF
Language of Original Document	English
Abbreviated Source Title	Solid State Sci.
Source	Scopus