Electronic structure of LiNiO2, LiFeO2 and LiCrO2: X-ray photoelectron and X-ray emission study / Galakhov V.R., Kurmaev E.Z., Uhlenbrock St., Neumann M., Kellerman D.G., Gorshkov V.S. // Solid State Communications. - 1995. - V. 95, l. 6. - P. 347-351.

ISSN:

00381098

Type:

Article

Abstract:

We present X-ray photoelectron (XPS) and soft X-ray emission (XES) spectra of LiNiO2, LiFeO2 and LiCrO2. The concentration of holes per oxygen ion in LiNiO2 is estimated and a classification of the investigated oxides is given. We propose, that LiFeO2 should be placed in the intermediate region between a charge-transfer and a Mott-Hubbard insulator and LiCrO2 can most likely be assigned to the Mott-Hubbard insulators. © 1995.

Author keywords:

Index keywords:

Activation energy; Charge transfer; Electric conductivity; Electron energy levels; Electronic structure; Emission spectroscopy; Heating; Parameter estimation; Synthesis (chemical); Thermal effects; X

DOI:

10.1016/0038-1098(95)00279-0

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0029360301&doi=10.1016%2f0038-1098%2895%2900279-0&partnerID=40&md5=38a37d94622da9796bfc67b250003b41

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0029360301&doi=10.1016%2f0038-1098%2895%2900279-0&partnerID=40&md5=38a37d94622da9796bfc67b250003b41
Affiliations	Institute of Metal Physics, Russian Academy of Sciences-Ural Division, 620219 Yekaterinburg, GSP-170, Russia; Fachbereich Physik, Universität Osnabrück, 49069 Osnabrück, Germany; Institute of Chemistry of Solids, Ural Division of Russian Academy of Sciences 620219 Yekaterinburg, GSP-145, Russia
References	Kuiper, Kruizinga, Ghijsen, Sawatzky, Verweij, (1989) Phys. Rev. Lett., 62, p. 221; Oku, Tlkuda, Hirokawa, (1991) J. Electron Spect. Relat. Phen., 53, p. 201; Tomellini, (1992) J. Electron Spect. Relat. Phen., 58, p. 75; Kemp, Cox, (1990) J. Phys.: Condens. Matter, 2, p. 9653; van Elp, Wieland, Eskes, Kuiper, Sawatzky, de Groot, Turner, (1991) Phys. Rev., 44 B, p. 6090; van Elp, Eskes, Kuiper, Sawatzky, (1992) Phys. Rev., 45 B, p. 1612; Anisimov, Zaanen, Andersen, (1991) Phys. Rev., 44 B, p. 943; Czyẑyk, Potze, Sawatzky, Band-theory description of high-energy spectroscopy and the electronic structure of LiCoO2 (1992) Physical Review B, 46 B, p. 3729; de Groot, (1991) Ph.D. Thesis, , University of Nijmegen; St.Uhlenbrock, M.Neumann (to be published); Zaanen, Sawatzky, Allen, (1985) Phys. Rev. Lett., 55, p. 418; Uhlenbrock, (1994) Ph.D. Thesis, , University of Osnabrück; Hüfner, Steiner, Sander, Neumann, (1991) S. Witzel, Z. Phys., 44 B, p. 943; Fujimori, Minami, (1984) Phys. Rev., 30 B, p. 957; Galakhov, Butorin, Kurmaev, Korotin, (1991) Physica, 168 B, p. 163; Mizokawa, Fujimori, Namatame, Akeyama, Kosugi, (1994) Phys. Rev., 49 B, p. 7193; Yeh, Lindau, (1985) Atomic Data and Nucl. Data Tables, 32, p. 1; Lad, Henrich, (1989) Phys. Rev., 39 B, p. 13478; Fujimori, Sealci, Kimizuka, Taniguchi, Suga, (1986) Phys. Rev., 34 B, p. 7318
Correspondence Address	Galakhov, V.R.
CODEN	SSCOA
Language of Original Document	English
Abbreviated Source Title	Solid State Commun
Source	Scopus