STUDY OF THE NATURE AND PROPERTIES OF V//1// minus //xCu//xO//2 SOLID SOLUTIONS (0 less than equivalent to X less than equivalent to 0. 04). / Kellerman D.G., Gorshkov V.S., Belysheva G.M., Khodos M.Ya., Perelyaev V.A. // Neorganiceskie materialy. - 1987. - V. 23, l. 10. - P. 1678-1682.

ISSN:

0002337X

Type:

Article

Abstract:

It is shown that for x less than equivalent to 0. 02 V//1// minus //xCu//xO//2 solid solutions (0 less than equivalent to x less than equivalent to 0. 04) are isostructural with pure vanadium dioxide. In the investigated samples a semiconductor-metal phase transition is observed. For x greater than 0. 02 a redistribution of the copper ions occurs. Copper additives lower the semiconductor-metal phase transition temperature and stabilize the intermediate insulating phase. The temperature dependence of the magnetic susceptibility of the semiconducting phase of V//1// minus //xCu//xO//2 attests to the formation of paramagnetic centers as a result of breakage of V**4** plus -V**4** plus bonds due to charge compensation. The number of paramagnetic centers is proportional to the copper concentration in the solid solution for x less than equivalent to 0. 02.

Author keywords:

Index keywords:

MAGNETIC MATERIALS - Paramagnetism; SOLID SOLUTIONS - Phase Transitions; VANADIUM COMPOUNDS - Additives; COPPER-DOPED VANADIUM DIOXIDE SOLID SOLUTIONS; INSULATING-PHASE STABILIZATION; PARAMAGNETIC CEN

DOI:

нет данных

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0023436394&partnerID=40&md5=d0042c8bf8b05138206800a44cfc1290

Соавторы в МНС:

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Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0023436394&partnerID=40&md5=d0042c8bf8b05138206800a44cfc1290
Correspondence Address	Kellerman, D.G.
CODEN	IVNMA
Language of Original Document	Russian
Abbreviated Source Title	Izv Akad Nauk SSSR Neorg Mater
Source	Scopus