Effect of surface modification of hydrated titanium dioxide on its selectivity to strontium / Voronina A.V., Semenishchev V.S. // Radiochemistry. - 2013. - V. 55, l. 1. - P. 94-97.

ISSN:
10663622
Type:
Article
Abstract:
The effect exerted on the selectivity of hydrated TiO2 to Sr by surface modification of the sorbent involving immobilization of mixed nickel potassium ferrocyanide was studied. The Sr specificity of the resulting sorbent (denoted as T-55) is comparable with that of hydrated TiO2: logK d (K d is Sr distribution coefficient, ml g-1) is 2.7 ± 0.2 in sorption from tap water with pH 7.8 ± 0.2, 2.7 ± 0.5 in sorption from CaCl2 solutions with pH 5.6 ± 0.2, and from 2.5 ± 0.8 to 1.7 ± 0.4 in sorption from CaCl 2 solutions with pH 7.0 ± 0.2. The modification makes the resulting T-55 sorbent selective to Sr in the presence of Ca at pH 5-6. © 2013 Pleiades Publishing, Ltd.
Author keywords:
hydrated titanium dioxide; nickel potassium ferrocyanide; sorption; strontium
Index keywords:
нет данных
DOI:
10.1134/S1066362213010189
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84874086948&doi=10.1134%2fS1066362213010189&partnerID=40&md5=5db9dd08119b92f20e21d19ac045c31e
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84874086948&doi=10.1134%2fS1066362213010189&partnerID=40&md5=5db9dd08119b92f20e21d19ac045c31e
Affiliations Yeltsin Ural Federal University, ul. Mira 19, Yekaterinburg 620002, Russian Federation
Author Keywords hydrated titanium dioxide; nickel potassium ferrocyanide; sorption; strontium
References Voronina A., .V., Semenishchev V., .S., Betenekov N., .D., (2010) Vopr. Radiats. Bezopasn., (3), pp. 54-61; Voronina, A.V., Semenishchev, V.S., Nogovitsyna, E.V., Betenekov, N.D., (2012) Radiokhimiya, 54 (1), pp. 66-70; Schwarzenbach, G., Flaschka, H., (1965) Die Komplexometrische Titration, , Enke Stuttgart; Denisova, T.A., (2009) Doctoral (Chem.) Dissertation, , Inst. of Solid State Chemistry, Ural Branch, Russian Acad. Sci. Yekaterinburg; Sharygin L., .M., Malykh T., .G., Dorofeev, Yu.A., Tret'Yakov, S.Ya., (1983) Adsorbts. Adsorb. (Kiev), (11), pp. 44-48
Correspondence Address Voronina, A.V.; Yeltsin Ural Federal University, ul. Mira 19, Yekaterinburg 620002, Russian Federation; email: a.voronina_v@mail.ru
CODEN RDIOE
Language of Original Document English
Abbreviated Source Title Radiochemistry
Source Scopus