Crystal structure of bis{(Z)-(benzyl-amino)[(5Z)-2-(benzylimino-κ N)-5-(2-methoxy-2-oxoethylidene)-4-oxothiolan-3-ylidene]methanethiolato-κS}copper(II) / Obydennov K., Khamidullina L., Slepukhin P., Morzherin Y., Lopez-Rodriguez M. // Acta Crystallographica Section E: Structure Reports Online. - 2015. - V. 71, l. 4. - P. m93-m94.

ISSN:

16005368

Type:

Article

Abstract:

The title complex, [Cu(C22H19N2O3S2)2], was obtained from the reaction between (Z)-methyl 2-(5-benzylimino-4-benzyl-carbamothioyl-3-oxothiolan-2-ylidene) acetate and Cu(NO3)2. The CuII atom is tetracoordinated by two N,S-bidentate ligands, forming a highly distorted tetrahedral environment. The structure displays two intramolecular N - H⋯O hydrogen bonds.

Author keywords:

Copper(II) complex; Crystal structure; Thioamide

Index keywords:

нет данных

DOI:

10.1107/S2056989015005022

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928151875&doi=10.1107%2fS2056989015005022&partnerID=40&md5=389c8f58e1999b872c481ec26ed20aa1

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928151875&doi=10.1107%2fS2056989015005022&partnerID=40&md5=389c8f58e1999b872c481ec26ed20aa1
Affiliations	Ural Federal University, Mira 19, Ekaterinburg, Russian Federation; I. Postovsky Institute of Organic Synthesis, Kovalevskoy 22, Ekaterinburg, Russian Federation; Universidad de La Laguna, Tenerife, Spain
Author Keywords	Copper(II) complex; Crystal structure; Thioamide
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Correspondence Address	Obydennov, K.; Ural Federal University, Mira 19, Russian Federation
Publisher	International Union of Crystallography
Language of Original Document	English
Abbreviated Source Title	Acta Crystallogr. Sect. E Struct. Rep. Online
Source	Scopus