3-Naphthoylindazoles and 2-naphthoylbenzoimidazoles as novel chemical groups of synthetic cannabinoids: Chemical structure elucidation, analytical characteristics and identification of the first representatives in smoke mixtures / Shevyrin V., Melkozerov V., Nevero A., Eltsov O., Morzherin Y., Shafran Y. // Forensic Science International. - 2014. - V. 242, l. . - P. 72-80.

ISSN:
03790738
Type:
Article
Abstract:
By means of gas chromatography with mass spectrometry detection (GC-MS), including high resolution mass spectrometry (GC-HRMS) together with ultra-high performance liquid chromatography in combination with high resolution tandem mass spectrometry (UHPLC-HRMS), nuclear magnetic resonance spectroscopy (NMR) and Fourier transform infrared spectroscopy (FT-IR), structure of novel synthetic cannabinoids, namely, 1-(5-fluoropentyl)-1. H-indazol-3-yl(naphthalen-1-yl)methanone, naphthalen-1-yl(1-pentyl-1. H-benzo[. d]imidazol-2-yl)methanone and 1-(5-fluoropentyl)-1. H-benzo[. d]imidazol-2-yl(naphthalen-1-yl)methanone was established. Analytical data obtained in the paper enable reliable identification of these compounds during qualitative analysis of seizures, including smoke mixtures. © 2014 Elsevier Ireland Ltd.
Author keywords:
Designer drugs; FT-IR; HRMS/MS; Identification; NMR
Index keywords:
1 (5 fluoropentyl) 1h benzo[d]imidazol 2 yl(naphthalen 1 yl)methanone; 1 (5 fluoropentyl) 1h indazol 3 yl(naphthalen 1 yl)methanone; 2 naphthoylbenzoimidazole derivative; 3 naphthoylindazole derivativ
DOI:
10.1016/j.forsciint.2014.06.02
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Affiliations Ural Federal University, Institute of Chemistry and Technology, 19 Mira Str., 620002 Ekaterinburg, Russian Federation; Expert and Criminalistic Center, Main Agency of the Ministry of the Interior of the Russian Federation, Sverdlovsk Region Branch, 17 Lenina Avenue, 620014 Ekaterinburg, Russian Federation; State Committee of Forensic Expertises of Republic of Belarus, 43 Kalvariyskaya Str., 220073 Minsk, Belarus; TOSLab. Ltd., Bldg. 1, 5 Initsiativnaia Str., 121357 Moscow, Russian Federation
Author Keywords Designer drugs; FT-IR; HRMS/MS; Identification; NMR
Chemicals/CAS cannabis, 8001-45-4, 8063-14-7; Cannabinoids; Designer Drugs
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Correspondence Address Shafran, Y.; Ural Federal University, Institute of Chemistry and Technology, 19 Mira Str., 620002 Ekaterinburg, Russian Federation; email: yuri.shafran@toslab.com
Publisher Elsevier Ireland Ltd
CODEN FSIND
PubMed ID 25036783
Language of Original Document English
Abbreviated Source Title Forensic Sci. Int.
Source Scopus