Electrochemical and spectroscopic properties of tellurium in fused alkali chlorides / Volkovich V.A., Kabaev G.K., Polovov I.B., Vasin B.D., Griffiths T.R. // ECS Transactions. - 2008. - V. 16, l. 49. - P. 335-341.

ISSN:

19385862

Type:

Conference Paper

Abstract:

The electrochemical and spectroscopic properties of tellurium were studied between 823 and 1123 K in alkali chloride melts based on 3LiCl-2KCl, NaCl-2CaCl and NaCl-KCl mixtures using potentiometry, cyclic voltammetry, anodic and cathodic polarization and absorption spectroscopy. Tellurium electrode potential values were measured at Te concentrations between 0.0006 and 0.008 mole fraction. Only Te(II) ions are present in chloride melts in the equilibrium with tellurium. Reactions of Te and Ag2Te with Cl2 and HCl were studied spectroscopically in NaCl-2CsCl melt at 823 K. ©The Electrochemical Society.

Author keywords:

Index keywords:

Alkali chloride melts; Alkali chlorides; Chloride melt; Electrode potentials; Mole fraction; Potentiometry; Spectroscopic property; Absorption spectroscopy; Calcium chloride; Cathodic polarization; Cy

DOI:

10.1149/1.3159338

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-77649169665&doi=10.1149%2f1.3159338&partnerID=40&md5=075c224b462693c713ed413e2da3c5de

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-77649169665&doi=10.1149%2f1.3159338&partnerID=40&md5=075c224b462693c713ed413e2da3c5de
Affiliations	Department of Rare Metals and Nanomaterials, Ural State Technical University-UPI, Ekaterinburg, 620002, Russian Federation; Redston Trevor Consulting, Ltd., Leeds, LS17 8RF, United Kingdom
References	N. J. Bjerrum, Inorg. Chem., 9, 1965 (1970); N. J. Bjerrum, G. P. Smith, J. Amer. Chem. Soc., 90, 4472 (1968); N. J. Bjerrum, G. P. Smith, C. R. Boston, Inorg. Chem., 6, 1162 (1967); J. H. von Barner, N. J. Bjerrum, ibid., 12, 1891 (1973); von Barner, J.H., Bjerrum, N.J., Kiens, K., (1974) Inorg. Chem, 13, p. 1708; Gruen, D.M., McBeth, R.L., Foster, M.S., Crouthamel, C.E., (1966) J. Phys. Chem, 70, p. 472
Correspondence Address	Volkovich, V. A.; Department of Rare Metals and Nanomaterials, Ural State Technical University-UPI, Ekaterinburg, 620002, Russian Federation
Sponsors	Physical and Analytical EIectrochemistry;High Temperature Materials;Electrodeposition;Energy Technology
Conference name	Molten Salts and Ionic Liquids 16 - 214th ECS Meeting
Conference date	12 October 2008 through 17 October 2008
Conference location	Honolulu, HI
Conference code	79406
ISBN	9781615676422
Language of Original Document	English
Abbreviated Source Title	ECS Transactions
Source	Scopus