Thermodynamic properties of lanthanum in gallium-indium eutectic based alloys / Shchetinskiy A.V., Dedyukhin A.S., Volkovich V.A., Yamshchikov L.F., Maisheva A.I., Osipenko A.G., Kormilitsyn M.V. // Journal of Nuclear Materials. - 2013. - V. 435, l. 1-3. - P. 202-206.

ISSN:

00223115

Type:

Article

Abstract:

Activity and activity coefficients of lanthanum were determined for the first time in gallium-indium eutectic based alloys in a wide temperature range employing electromotive force method. Activity of β-La and super cooled liquid lanthanum in Ga-In eutectic based alloys between 573 and 1073 K linearly depends on the reciprocal temperature: lgaβ-La(Ga-In)=5.660-15, 352T±0.093 lgaLa(Ga-In)=6.074-15,839T±0.093 Activity coefficients of β-La and super cooled liquid lanthanum in this system at 617-1073 K are described by the following equations: lgγβ-La (Ga-In)=3.786-12,216T±0.171 lgγLa(Ga-In)=4. 199-12,703T±0.171 In addition activity of lanthanum in alloys with In was also determined in the same temperature range. © 2012 Elsevier B.V. All rights reserved.

Author keywords:

Index keywords:

Electromotive force method; Reciprocal temperature; Supercooled liquids; Temperature range; Cerium alloys; Electromotive force; Eutectics; Gallium; Gallium alloys; Indium; Indium alloys; Lanthanum; Li

DOI:

10.1016/j.jnucmat.2012.12.035

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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84873841168&doi=10.1016%2fj.jnucmat.2012.12.035&partnerID=40&md5=1d65445e30249cf648d0bed12f1e530a

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84873841168&doi=10.1016%2fj.jnucmat.2012.12.035&partnerID=40&md5=1d65445e30249cf648d0bed12f1e530a
Affiliations	Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg 620002, Russian Federation; JSC State Scientific Centre, Research Institute of Atomic Reactors, Dimitrovgrad 433510, Russian Federation
References	Lebedev, V.A., (1993) Selectivity of Liquid Metal Electrodes in Fused Halides, , Metallurgiya Chelyabinsk (in Russian); (1996) ASM Binary Phase Diagrams, , Software, ASM, International; Gurvich, L.V., Weints, I.V., Medvedev, V.A., (1981) Thermodynamic Properties of Individual Compounds, 3 (PART. 2). , Nauka, Moskow (in Russian); Yatsenko, S.P., Anikin, A.Yu., Dieva, E.N., (1972) Dokl. Acad. Nauk SSSR, Metally, (2), p. 212; Kober, V.I., Nichkov, I.F., Raspopin, S.P., Taskaev, S.V., Dontsov, I.I., (1983) Alloys of Rare Metals with Specific Physical Properties, pp. 130-132. , Nauka, Moscow (in Russian); Vnuchkova, L.A., Bayanov, A.P., Serebryannikov, V.V., Phys, Zh., (1971) Zh. Phys. Khim., 45, p. 177; Degtyar, V.A., Bayanov, A.P., Vnuchkova, L.A., Serebrennikov, V.V., (1971) Izv. Acad. Nauk SSSR, Metally, (4), p. 149; Kober, V.I., Dubinin, V.A., Kochkin, V.I., Nichkov, I.F., Raspopin, S.P., (1983) Izv. Vuzov. Tsvet. Metallurgiya, (6), p. 113; Volkovich, V.A., Danilov, D.A., Vasin, B.D., Khokhryakov, A.A., (2006) Rasplavy, (4), p. 21; Volkovich, V.A., Vasin, B.D., Griffiths, T.R., Polovov, I.B., Medvedev, E.O., Yakimov, S.M., (2007) ECS Transactions, 3 (35), p. 493; Volkovich, V.A., Medvedev, E.O., Vasin, D.A., Danilov, B.D., (2006) Rasplavy, (5), p. 24; Glushko, V.N., (1978) Thermal Constants of Substances, 8 (PART 1). , AN SSSR, Moscow (in Russian)
Correspondence Address	Yamshchikov, L.F.; Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg 620002, Russian Federation; email: l.yamshchikov@gmail.com
CODEN	JNUMA
Language of Original Document	English
Abbreviated Source Title	J Nucl Mater
Source	Scopus