Phase relations in ternary oxide systems of III and VB group elements in the subsolidus region. Ternary oxide compounds / Zuev M.G. // Uspekhi Khimii. - 2000. - V. 69, l. 7. - P. 621-623.

ISSN:
00421308
Type:
Article
Abstract:
Phase relations in the subsolidus region are considered for 54 ternary systems including M2O3-V2O5-R2O 5, Y2O3 (La2O3, Sc2O3)-Nb2O5-Ta2O 5, M2O3-B2O3-R2O 5, M2O3-Ga2O3-R2O 5, Al2O3-V2O5-R2O 5, where Misa rare-earth element and R = Ta, Nb. Criteria for the formation of ternary oxide systems (size of cations and the ratio of the radii of ions forming the anionic part of compounds) are found. Crystal-chemical characteristics of MR2VO9, LaRB2O7, La4VBO10, Ln7VBO17 (Ln = La, Pr, Nd), and La3Ga5.5R0.5O14 are presented. The vibrational spectra of polycrystals of ternary oxide compounds and solid solutions based on them are described in detail.
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Affiliations Institute of Solid State Chemistry, Urals Br. of the Russ. Acad. of Sci., 91, Ul. Pervomaiskaya, 620219 Ekaterinburg, Russian Federation
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Correspondence Address Zuev, M.G.; Institute of Solid State Chemistry, Urals Br. of the Russ. Acad. of Sci., 91, Ul. Pervomaiskaya, 620219 Ekaterinburg, Russian Federation
CODEN USKHA
Language of Original Document Russian
Abbreviated Source Title Usp. Khim.
Source Scopus