Controllable changes in the porous structure of polymeric nuclear track membranes / Ovchinnikov V.V., Seleznev V.D., Surguchev V.V., Kuznetsov V.I. // Journal of Membrane Science. - 1991. - V. 55, l. 3. - P. 299-310.

ISSN:
03767388
Type:
Article
Abstract:
As has been shown earlier, by applying external tensile stresses to a polymeric membrane it is possible for the membrane as a whole to be deformed elastically, while in areas around pores stress arises that is close to the yield stress of the polymer. This leads to a large plastic deformation and to the growth of pores. Experimental investigation of the loading of polyethylene terephthalate nuclear membranes by excessive gas pressure has confirmed this assumption. Control of changes in the porous structure of membranes was carried out both according to the gas-dynamic pore radius and by the conventional Knudsen equation. It was found that an excess of pressure over some limiting value causes irreversible growth of the pores. The stabilization time of the porous structure (at room temperature) during loading was ca. 10 min. Investigations of changes in porous structure of nuclear membranes under load have been carried out over a wide range of pore size. The growth ratio of pores reached several hundred percent depending on the initial pore sizes and free surface of the membrane. © 1991.
Author keywords:
membrane deformation; Membrane preparation and structure; microporous and porous membranes; poly (ethylene terephthalate) membrane; tracketched membranes
Index keywords:
Plastics Films - Deformation; Polyethylene Terephthalates - Porosity; Membrane Deformation; Membrane Separation; Membrane Structure; Membranes; polymer; conference paper; membrane structure
DOI:
10.1016/S0376-7388(00)80584-0
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Поле Значение
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Affiliations Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, 141980 Dubna, Russian Federation; Department of Molecular Physics, Urals Polytechnical Institute, Sverdlovsk, Russian Federation
Author Keywords membrane deformation; Membrane preparation and structure; microporous and porous membranes; poly (ethylene terephthalate) membrane; tracketched membranes
References Ageev, Neverov, Strusovskaya, (1982) Formation of a microporous structure of poly(ethylene terephthalate) crystallizing in some solvents, 23, p. 75. , Vestn. Mosk. Univ; Krykin, Lomakin, Tigina, On processes of gas transfer through modified amorphous-crystalline polymeric membranes under high pressure conditions (1986) Zh. Fiz. Khim., 60, p. 878; Aleskerov, Volynskii, Bakeev, Influence of an adsorption-active medium on deformation of glassy poly(ethylene terephthalate) (1976) Vysokomol. Soedin., 18, p. 2121. , Ser. A; Volynskii, Loginov, The structure and adsorptive properties of glassy poly(ethylene terephthalate) deformed in an adsorption-active medium (1980) Vysokomol. Soedin., 22, p. 2727. , Ser. A; Volynskii, Kozlova, Lavrent'ev, Permeability of liquids through glassy poly(ethylene terephthalate) deformed in an adsorption-active medium (1985) Vysokomol. Soedin., 27, p. 2169. , Ser. A; (1980) Catalog Lab. 50, , Pleasanton, CA, U.S.A; Fisher, Spohr, Production and use of nuclear tracks imprinting structure on solids (1983) Reviews of Modern Physics, 55, p. 907; Flerov, Synthesis of superheavy elements and application of nuclear physics methods to adjacent fields (1984) Vestn. Akad. Nauk SSSR, 4, p. 35; (1989) Nuclear Track Membranes, , Booklet, Dubna, U.S.S.R; Ovchinnikov, The deformation mechanism of a porous structure of the poly(ethylene terephthalate) nuclear track membranes (1989) Ob'edin. Inst. Yad. Issled., , Dubna, U.S.S.R. [Prepr.], No. E12-89-762; Kuznetsov, Ovchinnikov, Porodnov, Investigation of deformation processes in a loaded nuclear track membrane (1989) J. Appl. Mech. and Techn. Phys., 3, p. 144. , Zh. Prikl. Mehan. i Tehn. Fiz; Kuznetsov, Ovchinnikov, Seleznev, Gas-dynamic check of pore radius in nuclear track membranes (1983) Inzh.-Fiz. Zh., 45, p. 332; Borisov, Kalinin, Porodnov, Suetin, Micromanometer with digital indication (1972) Prib. Tekh. Eksp., 4, p. 209; Tager, (1968) Fiziko-Khimiya Polimerov, , Moscow
Correspondence Address Ovchinnikov, V.V.; Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, 141980 Dubna, Russian Federation
CODEN JMESD
Language of Original Document English
Abbreviated Source Title J. Membr. Sci.
Source Scopus