Electrochemical properties of molybdenum in alkali chloride melts / Ivanov A.B., Volkovich V.A., Likhachev P.Yu., Kamalov R.V. // ECS Transactions. - 2014. - V. 64, l. 4. - P. 377-387.

ISSN:
19385862
Type:
Conference Paper
Abstract:
Behavior of molybdenum was studied in individual fused alkali chlorides and their mixtures employing electrochemical and spectroscopic techniques. Formal standard electrode potentials of molybdenum and thermodynamics of molybdenum chloride were obtained in molten LiCl, NaCl, KCl, RbCl, CsCl at 1123 K, NaCl- CsCl eutectic at 793-1023 K, NaCl-KCl equimolar mixture at 973- 1123 K, LiCl-KCl-CsCl eutectic at 633-1173 K. Diffusion coefficients of molybdenum ions were determined in LiCl-KCl- CsCl eutectic melt. Electronic absorption spectra of Mo(III) ions were measured in individual salts and their mixtures and spectroscopic parameters of MoCl6 3- complex ions determined. Copyright © 2014 by The Electrochemical Society. All rights reserved.
Author keywords:
Index keywords:
Absorption spectroscopy; Cesium alloys; Chlorine compounds; Diffusion; Eutectics; Fused salts; Ions; Metal ions; Mixtures; Molybdenum; Molybdenum compounds; Salts; Thermodynamics; Alkali chloride melt
DOI:
10.1149/06404.0377ecst
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921372999&doi=10.1149%2f06404.0377ecst&partnerID=40&md5=18ddd06ed9b13a3dca40f97cdceeb385
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Affiliations Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, Russian Federation
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Editors De Long H.C.Reichert W.M.Trulove P.C.Haverhals L.M.Mizuhata M.Mantz R.A.Ispas A.Bund A.
Sponsors Electrodeposition Electrodeposition Division of the Electrochemical Society;Energy Technology Division of the Electrochemical Society;Physical and Analytical Electrochemistry Division of the Electrochemical Society
Publisher Electrochemical Society Inc.
Conference name 19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting
Conference date 5 October 2014 through 9 October 2014
Conference code 110021
ISBN 9781623321819
Language of Original Document English
Abbreviated Source Title ECS Transactions
Source Scopus