Molybdenum(V) species in alkali chloride melts: An electronic absorption spectroscopy study / Kamalov R.V., Volkovich V.A., Ivanov A.B., Vasin B.D., Griffiths T.R. // ECS Transactions. - 2014. - V. 64, l. 4. - P. 189-195.

ISSN:

19385862

Type:

Conference Paper

Abstract:

Electronic absorption spectra of solutions of molybdenum pentachloride in fused alkali chlorides were studied between 450 and 850 °C. LiCl-KCl, NaCl-CsCl, NaCl-KCl-CsCl eutectics and NaCl-KCl equimolar mixture were used as solvents. Although the experimental spectra contain only one broad band in the visible region, resolving the spectra into overlapping bands revealed two individual components under the experimental band. The ratio of intensities of the constituent bands depends on temperature and they are attributed to the absorption of MoCl6 - ion and MoCl5 molecular species. Spectroscopic parameters of MoCl6 - were determined and MoCl6 -虠MoCl5 equilibrium is discussed. Absorption spectra of gaseous MoCl5 were also recorded. Copyright © 2014 by The Electrochemical Society. All rights reserved.

Author keywords:

Index keywords:

Absorption spectroscopy; Cesium alloys; Chemical analysis; Chlorine compounds; Electromagnetic wave absorption; Fused salts; Molybdenum; Salts; Alkali chloride melts; Electronic absorption spectra; El

DOI:

10.1149/06404.0189ecst

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921387435&doi=10.1149%2f06404.0189ecst&partnerID=40&md5=174f3c25434667ae735a78b4c97e61d8

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921387435&doi=10.1149%2f06404.0189ecst&partnerID=40&md5=174f3c25434667ae735a78b4c97e61d8
Affiliations	Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, Russian Federation; Redston Trevor Consulting Ltd., Leeds, United Kingdom
References	Carlin, R.T., Osteryoung, R.A., (1988) Inorg. Chem., 27, p. 1482; Barnard, P.A., Sun, I.W., Hussey, C.L., (1990) Inorg. Chem., 29, p. 3670; Gabriel, J.C., Vincent, D., Bouteillon, J., Poignet, J.C., Volkovich, V.A., Griffiths, T.R., (1999) Electrochim. Acta, 44, p. 4619; Aleksandrov, E.P., Alekseev, A.B., Vasin, B.D., Raspopin, S.P., (1981) Izv. Vuzov. Tsvet. Metallurgiya, (1), p. 66. , (in Russian); Volkovich, V.A., Polovov, I.B., Kamalov, R.V., Griffiths, T.R., (2010) ECS Trans., 33 (7), p. 391; Kamalov, R.V., Volkovich, V.A., Polovov, I.B., Vasin, B.D., (2012) Russian Metallurgy, (2), p. 114. , Metally; Volkovich, V.A., Vasin, B.D., Maltsev, D.S., Aleksandrov, D.E., (2013) Method of Cleaning Irradiated Nuclear Fuel; Horner, S.M., Tyree, S.Y., (1963) Inorg. Chem., 2, p. 568; Scheffler, T.B., Hussey, C.L., Seddon, K.R., Kear, C.M., Armitage, P.D., (1983) Inorg. Chem., 22, p. 2099; Volkovich, V.A., May, I., Charnock, J.M., Lewin, B., (2002) Phys. Chem. Chem. Phys., 4 (23), p. 5753; Volkovich, V.A., Polovov, I.B., Kamalov, R.V., Vasin, B.D., Griffiths, T.R., (2014) Molten Salts Chemistry and Technology, 489p. , M. Gaune-Escard and G.M. Haarberg, Editors, John Wiley & Sons Inc. Hoboken; Vasin, B.D., Maslov, S.V., Volkovich, V.A., Polovov, I.B., Kazakov, S.A., Rebrin, O.I., (2005) Proc. 7-th Int. Symp. Molten Salts Chem. Techn., 1, 335p. , P. Taxil, C. Bessada, M. Cassir and M. Gaune-Escard, Editors, Toulouse; Volkovich, V.A., Danilov, D.A., Polovov, I.B., Vasin, B.D., Griffiths, T.R., Aleksandrov, D.E., Tropin, O.A., Tsarevskii, D.V., (2007) ECS Transactions, 3 (35), p. 555; Bader, R.F.W., Westland, A.D., (1961) Can. J. Chem., 39, p. 2306
Editors	De Long H.C.Reichert W.M.Trulove P.C.Haverhals L.M.Mizuhata M.Mantz R.A.Ispas A.Bund A.
Sponsors	Electrodeposition Electrodeposition Division of the Electrochemical Society;Energy Technology Division of the Electrochemical Society;Physical and Analytical Electrochemistry Division of the Electrochemical Society
Publisher	Electrochemical Society Inc.
Conference name	19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting
Conference date	5 October 2014 through 9 October 2014
Conference code	110021
ISBN	9781623321819
Language of Original Document	English
Abbreviated Source Title	ECS Transactions
Source	Scopus