An electrochemical study of uranium (III) and (IV) species in fused alkali chlorides / Maltsev D.S., Volkovich V.A., Vladykin E.N., Vasin B.D. // ECS Transactions. - 2014. - V. 64, l. 4. - P. 357-367.

ISSN:

19385862

Type:

Conference Paper

Abstract:

The behavior of uranium(III) and (IV) chloro-species was studied in LiCl-KCl-CsCl eutectic melt between 573 and 1073 K by potentiometry, cyclic voltammetry and chronopotentiometry. Uranium formal standard electrode potentials and U(III)/U(IV) formal red-ox potentials in the given melt were determined and thermodynamic properties of uranium chlorides calculated. Diffusion coefficients of U(III) and U(IV) ions were determined employing cyclic voltammetry and chronopotentiometry measurements. Copyright © 2014 by The Electrochemical Society. All rights reserved.

Author keywords:

Index keywords:

Chlorine compounds; Diffusion; Fused salts; Ionic liquids; Salts; Thermodynamic properties; Uranium; Alkali chlorides; Chronopotentiometry; Electrochemical studies; Eutectic melt; LiCl-KCl; Potentiome

DOI:

10.1149/06404.0357ecst

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921348723&doi=10.1149%2f06404.0357ecst&partnerID=40&md5=47ee1e26cce13494f4b8670be4ffbb79

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921348723&doi=10.1149%2f06404.0357ecst&partnerID=40&md5=47ee1e26cce13494f4b8670be4ffbb79
Affiliations	Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, Russian Federation
Funding Details	MOE, Ministry of Education
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Editors	De Long H.C.Reichert W.M.Trulove P.C.Haverhals L.M.Mizuhata M.Mantz R.A.Ispas A.Bund A.
Sponsors	Electrodeposition Electrodeposition Division of the Electrochemical Society;Energy Technology Division of the Electrochemical Society;Physical and Analytical Electrochemistry Division of the Electrochemical Society
Publisher	Electrochemical Society Inc.
Conference name	19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting
Conference date	5 October 2014 through 9 October 2014
Conference code	110021
ISBN	9781623321819
Language of Original Document	English
Abbreviated Source Title	ECS Transactions
Source	Scopus