Spectroelectrochemical study of molybdenum containing chloride melts / Volkovich V.A., Vasin B.D., Tropin O.A., Danilov D.A., Raspopin S.P. // Russian Metallurgy (Metally). - 2010. - V. 2010, l. 2. - P. 150-153.

ISSN:
00360295
Type:
Article
Abstract:
The behaviour of molybdenum(III) and (IV) ions in NaCl-2CsCl eutectic based melts at 550-750°C was studied using high temperature spectroelectrochemistry and cyclic voltammetry. Anodic oxidation of Mo(III) ions yields Mo(IV) containing melts. Mo(IV) → Mo(III) recharge is reversible. The values of the formal standard Mo(IV)/Mo(III) red-ox potential, ΔG of formation and mixing MoCl4 in NaCl-2CsCl at 550°C are estimated. © 2010 Pleiades Publishing, Ltd.
Author keywords:
Index keywords:
Chloride melt; High temperature; Spectroelectrochemical study; Anodic oxidation; Cesium alloys; Cyclic voltammetry; Sodium chloride; Spectroelectrochemistry; Molybdenum
DOI:
10.1134/S003602951002014X
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Affiliations Ural State Technical University-UPI, Ekaterinburg, Russian Federation
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Correspondence Address Volkovich, V. A.; Ural State Technical University-UPI, Ekaterinburg, Russian Federation
Language of Original Document English
Abbreviated Source Title Russ. Metall. (Metally)
Source Scopus