X-ray and electronic absorption spectra of uranium in fused LiCl / Volkovich V.A., Maj I., Charnok G.M. // Rasplavy. - 2004. - V. , l. 2. - P. 76-85.

ISSN:

02350106

Type:

Article

Abstract:

The X-ray and electronic absorption spectra of the U(III), IV, V and (VĪ) chloride complexes in the fused LiCl at 1023 K and in the frozen LiCl are studied. A coordination surrounding of uranium and lengths of bonds of U-Cl and U-O in the complex ions are determined from the spectral data. It is revealed that the complexes of UO2Cl42- are formed upon interaction of UO3 and UO2 with LiCl. These complexes are being retained in the frozen substance but the bond length can be lowered somewhat.

Author keywords:

Index keywords:

Absorption spectroscopy; Chemical bonds; Chlorine compounds; Complexation; Ions; Lithium compounds; Spectrum analysis; Uranium compounds; X ray spectroscopy; Complex compounds; Fused salts

DOI:

нет данных

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-2942636159&partnerID=40&md5=d02a48b411184a84f0776a169f1d5f7e

Соавторы в МНС:

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Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-2942636159&partnerID=40&md5=d02a48b411184a84f0776a169f1d5f7e
Affiliations	Ural'skij GTU - UPI, Ekaterinburg, Russian Federation
Correspondence Address	Volkovich, V.A.; Ural'skij GTU - UPI, Ekaterinburg, Russian Federation
CODEN	RASPE
Language of Original Document	Russian
Abbreviated Source Title	Rasplavy
Source	Scopus