Electronic absorption spectra of melts based on sodium and cesium chlorides eutectic mixture containing tantalum / Vasin B.D., Maslov S.V., Volkovich V.A. // Rasplavy. - 1995. - V. , l. 2. - P. 47-49.

ISSN:
02350106
Type:
Article
Abstract:
An electronic absorption spectra of melts are received at 550°C in frequency range of 16300-30000 cm-1. The melt containing Ta(1V) ions was prepared by anodic dissolution of metal in fused salt-solvent. In order to prepare the salt mixture containing Ta(V) ions, a chlorination of metallic Ta in fused (Na-Cs)Cleut was performed preliminary. The extent of Ta oxidation and concentration were determined by the methods of oxidimetry and peroxide photometry respectively. Integral extent of Ta oxidation in electrolyte shows that Ta presences in the melt as (1V) state.
Author keywords:
Index keywords:
Cesium compounds; Electron spectroscopy; Eutectics; Frequency response; Fused salts; Impurities; Mixtures; Sodium chloride; Tantalum; Temperature control; Absorption spectra; Electrochemistry
DOI:
нет данных
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Affiliations Ural'skij Gosudarstvennyj, Tekhnicheskij Univ - UPI, Ekaterinburg, Russian Federation
Correspondence Address Vasin, B.D.; Ural'skij Gosudarstvennyj, Tekhnicheskij Univ - UPI, Ekaterinburg, Russian Federation
CODEN RASPE
Language of Original Document Russian
Abbreviated Source Title Rasplavy
Source Scopus