Dissolution of metallic niobium in molten eutectic sodium chloride-cesium chloride mixture containing bismuth (111) / Maslov S.V., Volkovich V.A., Vasin B.D. // Rasplavy. - 1994. - V. , l. 4. - P. 37-40.

ISSN:

02350106

Type:

Article

Abstract:

The oxidation of metallic niobium with bismuth (111)-ions in the fused eutectics (Na-Cs)Cl at 650°C is investigated by potentiometric, analytical and high spectroscopic methods. Spectral curves show the sharply defined maximum in the area near to 16000 and 22000 cm-1, dictated by d-d-transitions, and the edges of intensive bands on charge exchange. It is concluded that the coordinated complex niobium(111) ions are formed in the fused salt under oxidation of metallic Nb with Bi(111) ions.

Author keywords:

Index keywords:

Bismuth; Cesium compounds; Dissolution; Eutectics; Fused salts; Mixtures; Niobium; Oxidation; Sodium chloride; Spectroscopy; Potentiometry; Molten materials

DOI:

нет данных

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0028475149&partnerID=40&md5=a4da10b0a2aa5ab8427aad03ceec356f

Соавторы в МНС:

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Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0028475149&partnerID=40&md5=a4da10b0a2aa5ab8427aad03ceec356f
Affiliations	Ural'skij Gosudarstvennyj, Tekhnicheskij Univ, Ekaterinburg, Russian Federation
Correspondence Address	Maslov, S.V.; Ural'skij Gosudarstvennyj, Tekhnicheskij Univ, Ekaterinburg, Russian Federation
Publisher	Mezhdunarodnaya Kniga, Moscow, Russian Federation
CODEN	RASPE
Language of Original Document	Russian
Abbreviated Source Title	Rasplavy
Source	Scopus