Interaction of iron with the molten NaCl-KCl eutectic mixture containing nickel ions / Shardakov N.T., Shardakova G.N., Kudyakov V.Ya., Molchanova N.G., Zyryanov V.G. // Protection of Metals. - 1999. - V. 35, l. 1. - P. 47-50.

ISSN:
00331732
Type:
Article
Abstract:
It was shown that iron interacts with the molten eutectic mixture of sodium and potassium chlorides, containing nickel ions, in two stages. The first stage consist in the reduction of nickel and its alloying with iron. Because of the high reduction rate, nickel's activity, upon the completion of the stage, is different at different points of the substrate. At the second stage, the activities of nickel and iron are levelled by the transfer of their ions through the melt.
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Affiliations Inst. of High-Temp. Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Ekaterinburg, 620219, Russian Federation
References Ozeryanaya, I.N., Manukhina, T.I., Shardakova, G.N., (1990) Rasplavy, (6), p. 70; Smirnov, M.V., (1973) Elektrodnye Potentsialy v Rasplavlennykh Khloridakh (Electrode Potentials in Molten Chlorides), , Moscow: Nauka; Rozlovskii, A.A., (1976) IV Vsesoyuznaya Konferentsiya po Fizicheskoi Khimii Ionnykh Rasplavov i Tverdykh Elektrolitov (III All-Union Conf. on the Physical Chemistry of Ionic Melts and Solid-State Electrolytes), (PART 2). , Abstracts of Papers, Kiev; Baraboshkin, A.N., (1976) Elektrokristallizatsiya Metallov iz Rasplavlennykh Solei (Electrocrystallization of Metals from Molten Salts), , Moscow: Nauka; Nicki, J.J., Stammel, E., Krause, H.U., (1977) J. Cryst. Growth, 38 (3), p. 317; Vetter, K., (1961) Elektrochemische Kinetik (Electrochemical Kinetics), , Berlin: Springer; Ozeryanaya, I.N., Shardakov, N.T., Zyryanov, V.G., (1982) Mekhanizm Vzaimodeistviya Alyuminiya s Rasplavlennoi Evtekticheskoi Smes'yu Khloridov Litiya i Kaliya (Mechanism of Interaction of Aluminum with A Melted Eutectic LiCl-KCl Mixture), (5759). , Available from VINITI, Moscow; Shardakova, G.N., Manukhina, T.I., Ozeryanaya, I.N., (1986) Vysokotemperaturnaya Elektrokhimiya. Elektrolity. Kinetika (High-Temperature Electrochemistry. Electrolytes. Kinetics), p. 17. , Sverdlovsk
Correspondence Address Shardakov, N.T.; Inst. of High-Temp. Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Ekaterinburg, 620219, Russian Federation
Language of Original Document English
Abbreviated Source Title Prot. Met.
Source Scopus