Effect of pH on the electrodeposition kinetics of copper from acetate and sulfosalicylate complex solutions / Ostanina T.N., Uritskaya A.A., Rudoi V.M., Ostanin N.I., Ryabova O.V. // Russian Chemical Bulletin. - 2014. - V. 63, l. 7. - P. 1498-1503.

ISSN:

10665285

Type:

Article

Abstract:

A method was proposed for the calculation of partial currents that characterize the discharge of individual complex copper ions in acetate and sulfosalicylate solutions. The reaction rate constants for the electrodeposition of different forms of the copper complexes were determined using this method and results of the analytical calculation of the solution compositions depending on the pH. Fine-grained deposits with high adhesion to the surface were obtained from acetate (pH 4.7) and sulfosalicylate (pH 6.6) solutions in which the electrodeposition proceeds at high polarization due to low discharge rate constants of the anionic copper complexes. © 2014 Springer Science+Business Media New York.

Author keywords:

acetate complexes; calculation of fractional concentration; electrodeposition; kinetics; sulfosalicylate complexes

Index keywords:

нет данных

DOI:

10.1007/s11172-014-0626-3

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84924261145&doi=10.1007%2fs11172-014-0626-3&partnerID=40&md5=c6c6f0dcf571ef0ebc438ad9d0855880

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84924261145&doi=10.1007%2fs11172-014-0626-3&partnerID=40&md5=c6c6f0dcf571ef0ebc438ad9d0855880
Affiliations	Ural Federal University Named after the First President of Russia B. N. Yeltsin, 19 ul. Mira, Ekaterinburg, Russian Federation
Author Keywords	acetate complexes; calculation of fractional concentration; electrodeposition; kinetics; sulfosalicylate complexes
References	Ovchinnikova, S.N., Poddubnyi, N.P., Maslii, A.I., (2003) Russ. J. Electrochem. (Engl. Transl.), 39, p. 679. , 1:CAS:528:DC%2BD3sXksFShtLs%3D [Elektrokhimiya, 2003, 39, 752]; Butler, J.N., (1964) Ionic Equilibrium: A Mathematical Approach, , Addison-Wesley Reading, EUA; Tsupak, T.E., Bek, R.Y., Wei, D., Shuraeva, L.I., (2001) Russ. J. Electrochem. (Engl. Transl.), 37, p. 730. , 1:CAS:528:DC%2BD3MXmtFegtLg%3D [Elektrokhimiya, 2001, 37, 855]; Ovchinnikova, S.N., Poddubnyi, N.P., Maslii, A.I., Boldyrev, V.V., Schwarzacher, W., (2002) Russ. J. Electrochem. (Engl. Transl.), 38, p. 1210. , 1:CAS:528:DC%2BD38XoslSmtr0%3D [Elektrokhimiya, 2002, 38, 1339]; Ostanina, T.N., Uritskaya, A.A., Ostanin, N.I., Ryabo-va, O.V., Nikitina, I.A., (2013) Vestnik Tambov. Gos. Un-ta, 18, p. 2233. , [Bulletin of Tambov State Univ.]; Nikol'Skii, B.P., (1964) Spravochnik Khimika, , (eds) 2nd ed. Khimiya Moscow [Chemist's Manual]; Laitinen, H.A., Harris, W.E., (1975) Chemical Analysis; Sukhotin, A.M., (1981) Spravochnik Po Elektrokhimii, , (eds) [Manual on Electrochemistry]; Gamburg, Y.D., (1997) Elektrokhimicheskaya Kristallizatsiya Metallov i Splavov, , Yanus-K Moscow [Electrochemical Crystallization of Metals and Alloys]; Kravtsov, V.I., (1969) Elektrodnye Protsessy v Rastvorakh Kompleksov Metallov, , LGU Leningrad [Electrode Processes in Solutions of Metal Complexes]
Publisher	Springer New York LLC
CODEN	RCBUE
Language of Original Document	English
Abbreviated Source Title	Russ. Chem. Bull.
Source	Scopus