"Hairy" poly(3-hexylthiophene) particles prepared via surface-initiated Kumada catalyst-transfer polycondensation / Senkovskyy V., Tkachov R., Beryozkina T., Komber H., Oertel U., Horecha M., Bocharova V., Stamm M., Gevorgyan S.A., Krebs F.C., Kiriy A. // Journal of the American Chemical Society. - 2009. - V. 131, l. 45. - P. 16445-16453.

ISSN:
00027863
Type:
Article
Abstract:
Herein, we present a new paradigm in the engineering of nanostructured hybrids between conjugated polymer and inorganic materials via a chain-growth surface-initiated Kumada catalyst-transfer polycondensation (SI-KCTP) from particles. Poly(3-hexylthiophene), P3HT, a benchmark material for organic electronics, was selectively grown by SI-KCTP from (nano)particles bearing surface-immobilized Ni catalysts supported by bidentate phosphorus ligands, that resulted in hairy (nano)particles with end-tethered P3HT chains. Densely grafted P3HT chains exhibit strongly altered optical properties compared to the untethered counterparts (red shift and vibronic fine structure in absorption and fluorescence spectra), as a result of efficient planarization and chain-aggregation. These effects are observed in solvents that are normally recognized as good solvents for P3HT (e.g., tetrahydrofurane). We attribute this to strong interchain interactions within densely grafted P3HT chains, which can be tuned by changing the surface curvature (or size) of the supporting particle. The hairy P3HT nanoparticles were successfully applied in bulk heterojunction solar cells. © 2009 American Chemical Society.
Author keywords:
Index keywords:
Absorption and fluorescence spectra; Bearing surfaces; Bulk heterojunction solar cells; Fine structures; Growth surfaces; Inorganic materials; Interchain interactions; Nano-structured; Ni catalysts; O
DOI:
10.1021/ja904885w
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-70450190962&doi=10.1021%2fja904885w&partnerID=40&md5=aa95d2bfe98ac668958c022eab2fd777
Affiliations Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069 Dresden, Germany; Risø National Laboratory for Sustainable Energy, Technical University of Denmark, Frederiksborgvej 399, DK-4000 Roskilde, Denmark
Chemicals/CAS Nickel, 7440-02-0; Thiophenes; poly(3-hexylthiophene)
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Correspondence Address Kiriy, A.; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069 Dresden, Germany; email: kiriy@ipfdd.de
CODEN JACSA
PubMed ID 19860410
Language of Original Document English
Abbreviated Source Title J. Am. Chem. Soc.
Source Scopus