
<div class="publication-info">
	<h3>Electrical potential near hydrated surface of ordered mesoporous molecular sieves assessed by EPR of molecular pH-probes / Kovaleva E.G., Molochnikov L.S., Golovkina E.L., Hartmann M., Kirilyuk I.A., Grigoriev I.A. // Microporous and Mesoporous Materials. - 2015. - V. 203, l. C. - P. 1-7.</h3>
	<dl>
		<dt>ISSN:</dt><dd>13871811</dd>
		<dt>Type:</dt><dd>Article</dd>
				<dt>Abstract:</dt><dd>Some of the most important parameters of mesoporous materials are Stern potential of double electrical layer (DEL) and surface charge because of the pivotal role they play in the adsorption of charged molecular species. There are not any conventional and easy-to-perform techniques used to measure Stern potential in porous systems. The purpose of this work is to measure Stern potential in a specific case, i.e., practically cylindrical nanosized hydrated channels of the mesoporous molecular sieves (MMS) MCM-41 and SBA-15 with channel diameters ranging from 2.3 to 8.1 nm using pH-sensitive nitroxide radicals (NR). A technique for direct measurement of the near-surface (Stern) potential using pH-sensitive NR was developed. Negative and positive values of Stern potential for the positively and negatively charged surface of MMS channels were found. The ranges of pH of external solution for the near-zero charge, boost-charging of the channel surface and for dissociation of functional groups in the MMS studied were found. © 2014 Elsevier Inc. All rights reserved.</dd>
		<dt>Author keywords:</dt><dd>Double electrical layer; Ordered mesoporous materials; pH-sensitive nitroxide radicals; Zeta, Stern, Surface electrical potentials</dd>
		<dt>Index keywords:</dt><dd>Hydration; Molecular sieves; pH sensors; Sieves; Double electrical layer; Electrical potential; External solutions; Mesoporous molecular sieves; Negatively charged surfaces; Nitroxide radicals; Ordere</dd>
		<dt>DOI:</dt><dd>10.1016/j.micromeso.2014.10.01</dd>
		<dt>Смотреть в Scopus:</dt>
			<dd>
								<a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-84926187477&doi=10.1016%2fj.micromeso.2014.10.010&partnerID=40&md5=7cfa934af242939d85129435c56b4a2f" target="_blank">https://www.scopus.com/inward/record.uri?eid=2-s2.0-84926187477&amp;doi=10.1016%2fj.micromeso.2014.10.010&amp;partnerID=40&amp;md5=7cfa934af242939d85129435c56b4a2f</a>
							</dd>

		<dt>Соавторы в МНС:</dt>
		<dd>
		&mdash;		</dd>

				<dt>Другие поля</dt>
		<dd>
			<table class="v-table">
			<thead>
				<tr>
					<td class="w8 gar">Поле</td>
					<td>Значение</td>
				</tr>
			</thead>
			<tbody>
								<tr>
						<td class="gar">Link</td>
						<td>https://www.scopus.com/inward/record.uri?eid=2-s2.0-84926187477&doi=10.1016%2fj.micromeso.2014.10.010&partnerID=40&md5=7cfa934af242939d85129435c56b4a2f</td>
					</tr>
										<tr>
						<td class="gar">Affiliations</td>
						<td>Institute of Chemical Engineering, Ural Federal University, Mira St., 19, Yekaterinburg, Russian Federation; Department of Inorganic and General Chemistry, Ural State Forest Engineering University, Siberian Highway, 37, Yekaterinburg, Russian Federation; Erlangen Catalysis Resource Center (ECRC), Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstraße 3, Erlangen, Germany; Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Akad. Lavrent'ev Av., 9, Novosibirsk, Russian Federation</td>
					</tr>
										<tr>
						<td class="gar">Author Keywords</td>
						<td>Double electrical layer; Ordered mesoporous materials; pH-sensitive nitroxide radicals; Zeta, Stern, Surface electrical potentials</td>
					</tr>
										<tr>
						<td class="gar">Funding Details</td>
						<td>MOE, Russian Foundation for Basic Research; 14-03-00898, RFBR, Russian Foundation for Basic Research</td>
					</tr>
										<tr>
						<td class="gar">References</td>
						<td>Hartmann, M., Prakash, A.M., (2002) Catal. Today, 2854, p. 1; Hartmann, M., Vinu, A., Elangovan, S.P., (2002) J. Chem. Soc. Chem. Commun., p. 1238; Hartmann, M., Vinu, A., (2002) Langmuir, 18, p. 8010; Vinu, A., Murugesan, V., Hartmann, M., (2003) Chem. Mater., 15, p. 1385; Hartmann, M., Vinu, A., Elangovan, S.P., Murugesan, V., Böhlmann, W., (2002) Chem. Commun., p. 1238; Luan, Z., Hartmann, M., Zhao, D., Zhou, W., Kevan, L., (1999) Chem. Mater., 11, p. 1621; Molochnikov, L.S., Kovalyova, E.G., Grigor'Ev, I.A., Zagorodni, A.A., (2004) J. Phys. Chem. B, 108 (4), pp. 1302-1313; Kovalyova, E., Petkevich, T., Medyantseva, E., Molochnikov, L., (2006) Russ. J. Sorp. & Chromat. Processes, 6, p. 991; Kovaleva, E.G., Molochnikov, L.S., Nitroxides: Theory (2012) Experiment and Applications, pp. 211-246. , A.I. Kokorin, InTech Publisher Croatia; Parshina, E.V., Molochnikov, L.S., Kovaleva, E.G., Shishmakov, A.B., (2011) Russ. J. Phys. Chem. A, 85 (3), p. 452; Karge, H.G., Hatada, K., Zhang, Y., Fiederow, R., (1983) Zeolites, 3, p. 13; Lednor, P.W., (1991) J. Chem. Soc., p. 1625; Lednor, P.W., (1992) Catal. Today, 15, p. 243; Vinu, A., Streb, Ch., Murugesan, V., Hartmann, M., (2003) J. Phys. Chem. B, 107, pp. 8297-8299; Vinu, A., Murugesan, V., Hartmann, M., (2004) J. Phys. Chem. B, 108, pp. 7323-7330; Khramtsov, V., Weiner, L., Grigor'Ev, I., (1982) Chem. Phys. Lett., 91, p. 69; Smirnov, A.I., Ruuge, A., Reznikov, V.A., Voinov, M.A., Grigor'Ev, I.A., (2004) J. Am. Chem. Soc., 126, p. 8872; Khramtsov, V.V., Marsh, D., Weiner, L., (1992) Biochim. Biophys. Acta, 1104, p. 317; Roshchupkina, G.I., Bobro, A.A., Bratasz, A., Reznikov, V.A., Kuppusamy, P., Khramtsov, V.V., (2008) Free Radical Biol. Med., 45, p. 312; Voinov, M.A., Kirilyuk, I.A., Smirnov, A.I., (2009) J. Phys. Chem. B, 113 (11), pp. 3453-3460; Kovaleva, E.G., Molochnikov, L.S., Golovkina, E.L., Hartmann, M., Kirilyuk, I.A., Grigoriev, I.A., (2013) Micropor. Mesopor. Mater., 179, pp. 258-264; Etkins, P., (1980) Physical Chemistry, 2. , Mir Moscow (in Russian); Fridrechsberg, D.A., (1984) Colloid Chemistry Course: Textbook for Higher Education Institutions, , second ed. Khimiya Leningrad (in Russian); Helmhotz, H., (1879) Wied. Ann., 7, p. 337; Guye, G., (1910) J. Phys. Radium., 9, p. 457; Chapman, D.L., (1913) Phil. Mag., 25 (6), p. 457; Stern, O., (1924) Z. Electrochem., 30, p. 508; Frolov, Yu.G., (1989) Course of Colloid Chemistry: Surface Phenomena and Dispersive Systems, p. 464. , second ed., Moscow, Khimyia (in Russian); Ayler, R., (1982) Chemistry of Silica, , Mir Moscow (in 2 parts, P.2); Fernandez, M.S., Fromherz, P., (1977) J. Phys. Chem., 81 (18), pp. 1755-1761; Fromherz, P., (1989) Methods Enzymol., 171, pp. 376-387; Cevc, G., Marsh, D., (1987) Phospolipid Bilayers, Physical Principles and Models, , Wiley-Interscience New York; Khramtsov, V.V., March, D., Weiner, L., Reznikov, V.A., (1992) Biochim. Biophys. Acta, 1104 (2), pp. 317-324; Khramtsov, V.V., Volodarsky, L.B., Spin labeling (1998) The Next Millennium, Biological Magnetic Resonance, 14, p. 109. , L.J. Berliner, Plenum Press New York; Voinov, M.A., Rivera, I., Smirnov, A.I., (2013) Biophys. J., 104, pp. 106-116; Griffith, O.H., Dehlinger, P.J., Van, S.P., (1974) J. Membr. Biol., 15 (1), pp. 159-192; Kletskin, V.K., Polienko, J.F., Voinov, M.A., Smirnov, A.I., Chechik, V., (2008) Langmuir, 24, pp. 609-612; McHedlov-Petrosyan, N.O., (2005) Visn. Khark. Univ., 648 (12), pp. 27-31; Kirilyuk, I.A., Bobko, A.A., Khramtsov, V.V., Grigor'Ev, I.A., (2005) Org. Biomol. Chem., 7, pp. 1269-1274; Kirilyuk, I.A., Shevelev, T.G., Morozov, D.A., Khromovskih, E.L., Skuridin, N.G., Khramtsov, V.V., Grigor'Ev, I.A., (2003) Synthesis, 6, pp. 871-878; Hartmann, M., Racouchot, S., Bischof, C., (1999) Micropor. Mesopor. Mater., 27, pp. 309-320; Vinu, A., Böhlmann, W., Hartmann, M., (2004) J. Phys. Chem. B, 108, p. 11496; Budil, D.E., Sanghyuk, L., Saxena, S., Freed, J.H., (1996) J. Magn. Reson. Ser. A, 120, pp. 155-189; Tichomolova, K.P., (1989) Elecroosmos, , Khimiya Leningrad (in Russian); Smirnov, P., Yamaguchi, T., Kittaka, S., Takahara, S., Kuroda, Y., (2000) J. Phys. Chem. B, 104 (23), pp. 5498-5504; Deryagin, B.V., Churaev, N.V., Muller, V.M., (1985) Surface Forces, , Nauka Moscow (in Russian); Hansen, E.W., Stöcker, M., Schmidt, R., (1996) J. Phys. Chem., 100 (6), pp. 2195-2200; Tamashiro, M.N., Henriques, V.B., Lamy, M.T., (2005) Langmuir, 21 (24), pp. 11005-11016; Golovkina, E.L., Kovaleva, E.G., Molochnikov, L.S., Hartmann, M., Kirilyuk, I.A., Grigoriev, I.A., (2008) Russ. J. Sorp. & Chromat. Processes, 8 (6), pp. 971-985. , (in Russian); Morishige, K., Nobuoka, K., (1997) J. Chem. Phys., 107, pp. 6965-6971; Takahara, S., Sumiyama, N., Kittaka, S., (2005) J. Phys. Chem. B, 109 (22), pp. 11231-11239; Khramtsov, V.V., Volodarsky, L.B., (2002) Biol. Magn. Res., 14, pp. 109-180; Deere, J., Magner, E., Wall, J.G., Holdnett, B.K., (2002) J. Phys. Chem. B, 106 (29), pp. 7340-7347; Macdonald, I.D.C., Smith, W.E., (1996) Langmuir, 12, p. 706; Wilson, K.P., Malcolm, B.A., Matthews, B.W., (1992) J. Biol. Chem., 267, p. 10842</td>
					</tr>
										<tr>
						<td class="gar">Correspondence Address</td>
						<td>Kovaleva, E.G.; Institute of Chemical Engineering, Ural Federal University, Mira St., 19, Russian Federation</td>
					</tr>
										<tr>
						<td class="gar">Publisher</td>
						<td>Elsevier</td>
					</tr>
										<tr>
						<td class="gar">CODEN</td>
						<td>MIMMF</td>
					</tr>
										<tr>
						<td class="gar">Language of Original Document</td>
						<td>English</td>
					</tr>
										<tr>
						<td class="gar">Abbreviated Source Title</td>
						<td>Microporous Mesoporous Mater.</td>
					</tr>
										<tr>
						<td class="gar">Source</td>
						<td>Scopus</td>
					</tr>
								</tbody>
			</table>
		</dd>
			</dl>

</div>
Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84926187477&doi=10.1016%2fj.micromeso.2014.10.010&partnerID=40&md5=7cfa934af242939d85129435c56b4a2f
Affiliations	Institute of Chemical Engineering, Ural Federal University, Mira St., 19, Yekaterinburg, Russian Federation; Department of Inorganic and General Chemistry, Ural State Forest Engineering University, Siberian Highway, 37, Yekaterinburg, Russian Federation; Erlangen Catalysis Resource Center (ECRC), Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstraße 3, Erlangen, Germany; Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Akad. Lavrent'ev Av., 9, Novosibirsk, Russian Federation
Author Keywords	Double electrical layer; Ordered mesoporous materials; pH-sensitive nitroxide radicals; Zeta, Stern, Surface electrical potentials
Funding Details	MOE, Russian Foundation for Basic Research; 14-03-00898, RFBR, Russian Foundation for Basic Research
References	Hartmann, M., Prakash, A.M., (2002) Catal. Today, 2854, p. 1; Hartmann, M., Vinu, A., Elangovan, S.P., (2002) J. Chem. Soc. Chem. Commun., p. 1238; Hartmann, M., Vinu, A., (2002) Langmuir, 18, p. 8010; Vinu, A., Murugesan, V., Hartmann, M., (2003) Chem. Mater., 15, p. 1385; Hartmann, M., Vinu, A., Elangovan, S.P., Murugesan, V., Böhlmann, W., (2002) Chem. Commun., p. 1238; Luan, Z., Hartmann, M., Zhao, D., Zhou, W., Kevan, L., (1999) Chem. Mater., 11, p. 1621; Molochnikov, L.S., Kovalyova, E.G., Grigor'Ev, I.A., Zagorodni, A.A., (2004) J. Phys. Chem. B, 108 (4), pp. 1302-1313; Kovalyova, E., Petkevich, T., Medyantseva, E., Molochnikov, L., (2006) Russ. J. Sorp. & Chromat. Processes, 6, p. 991; Kovaleva, E.G., Molochnikov, L.S., Nitroxides: Theory (2012) Experiment and Applications, pp. 211-246. , A.I. Kokorin, InTech Publisher Croatia; Parshina, E.V., Molochnikov, L.S., Kovaleva, E.G., Shishmakov, A.B., (2011) Russ. J. Phys. Chem. A, 85 (3), p. 452; Karge, H.G., Hatada, K., Zhang, Y., Fiederow, R., (1983) Zeolites, 3, p. 13; Lednor, P.W., (1991) J. Chem. Soc., p. 1625; Lednor, P.W., (1992) Catal. Today, 15, p. 243; Vinu, A., Streb, Ch., Murugesan, V., Hartmann, M., (2003) J. Phys. Chem. B, 107, pp. 8297-8299; Vinu, A., Murugesan, V., Hartmann, M., (2004) J. Phys. Chem. B, 108, pp. 7323-7330; Khramtsov, V., Weiner, L., Grigor'Ev, I., (1982) Chem. Phys. Lett., 91, p. 69; Smirnov, A.I., Ruuge, A., Reznikov, V.A., Voinov, M.A., Grigor'Ev, I.A., (2004) J. Am. Chem. Soc., 126, p. 8872; Khramtsov, V.V., Marsh, D., Weiner, L., (1992) Biochim. Biophys. Acta, 1104, p. 317; Roshchupkina, G.I., Bobro, A.A., Bratasz, A., Reznikov, V.A., Kuppusamy, P., Khramtsov, V.V., (2008) Free Radical Biol. Med., 45, p. 312; Voinov, M.A., Kirilyuk, I.A., Smirnov, A.I., (2009) J. Phys. Chem. B, 113 (11), pp. 3453-3460; Kovaleva, E.G., Molochnikov, L.S., Golovkina, E.L., Hartmann, M., Kirilyuk, I.A., Grigoriev, I.A., (2013) Micropor. Mesopor. Mater., 179, pp. 258-264; Etkins, P., (1980) Physical Chemistry, 2. , Mir Moscow (in Russian); Fridrechsberg, D.A., (1984) Colloid Chemistry Course: Textbook for Higher Education Institutions, , second ed. Khimiya Leningrad (in Russian); Helmhotz, H., (1879) Wied. Ann., 7, p. 337; Guye, G., (1910) J. Phys. Radium., 9, p. 457; Chapman, D.L., (1913) Phil. Mag., 25 (6), p. 457; Stern, O., (1924) Z. Electrochem., 30, p. 508; Frolov, Yu.G., (1989) Course of Colloid Chemistry: Surface Phenomena and Dispersive Systems, p. 464. , second ed., Moscow, Khimyia (in Russian); Ayler, R., (1982) Chemistry of Silica, , Mir Moscow (in 2 parts, P.2); Fernandez, M.S., Fromherz, P., (1977) J. Phys. Chem., 81 (18), pp. 1755-1761; Fromherz, P., (1989) Methods Enzymol., 171, pp. 376-387; Cevc, G., Marsh, D., (1987) Phospolipid Bilayers, Physical Principles and Models, , Wiley-Interscience New York; Khramtsov, V.V., March, D., Weiner, L., Reznikov, V.A., (1992) Biochim. Biophys. Acta, 1104 (2), pp. 317-324; Khramtsov, V.V., Volodarsky, L.B., Spin labeling (1998) The Next Millennium, Biological Magnetic Resonance, 14, p. 109. , L.J. Berliner, Plenum Press New York; Voinov, M.A., Rivera, I., Smirnov, A.I., (2013) Biophys. J., 104, pp. 106-116; Griffith, O.H., Dehlinger, P.J., Van, S.P., (1974) J. Membr. Biol., 15 (1), pp. 159-192; Kletskin, V.K., Polienko, J.F., Voinov, M.A., Smirnov, A.I., Chechik, V., (2008) Langmuir, 24, pp. 609-612; McHedlov-Petrosyan, N.O., (2005) Visn. Khark. Univ., 648 (12), pp. 27-31; Kirilyuk, I.A., Bobko, A.A., Khramtsov, V.V., Grigor'Ev, I.A., (2005) Org. Biomol. Chem., 7, pp. 1269-1274; Kirilyuk, I.A., Shevelev, T.G., Morozov, D.A., Khromovskih, E.L., Skuridin, N.G., Khramtsov, V.V., Grigor'Ev, I.A., (2003) Synthesis, 6, pp. 871-878; Hartmann, M., Racouchot, S., Bischof, C., (1999) Micropor. Mesopor. Mater., 27, pp. 309-320; Vinu, A., Böhlmann, W., Hartmann, M., (2004) J. Phys. Chem. B, 108, p. 11496; Budil, D.E., Sanghyuk, L., Saxena, S., Freed, J.H., (1996) J. Magn. Reson. Ser. A, 120, pp. 155-189; Tichomolova, K.P., (1989) Elecroosmos, , Khimiya Leningrad (in Russian); Smirnov, P., Yamaguchi, T., Kittaka, S., Takahara, S., Kuroda, Y., (2000) J. Phys. Chem. B, 104 (23), pp. 5498-5504; Deryagin, B.V., Churaev, N.V., Muller, V.M., (1985) Surface Forces, , Nauka Moscow (in Russian); Hansen, E.W., Stöcker, M., Schmidt, R., (1996) J. Phys. Chem., 100 (6), pp. 2195-2200; Tamashiro, M.N., Henriques, V.B., Lamy, M.T., (2005) Langmuir, 21 (24), pp. 11005-11016; Golovkina, E.L., Kovaleva, E.G., Molochnikov, L.S., Hartmann, M., Kirilyuk, I.A., Grigoriev, I.A., (2008) Russ. J. Sorp. & Chromat. Processes, 8 (6), pp. 971-985. , (in Russian); Morishige, K., Nobuoka, K., (1997) J. Chem. Phys., 107, pp. 6965-6971; Takahara, S., Sumiyama, N., Kittaka, S., (2005) J. Phys. Chem. B, 109 (22), pp. 11231-11239; Khramtsov, V.V., Volodarsky, L.B., (2002) Biol. Magn. Res., 14, pp. 109-180; Deere, J., Magner, E., Wall, J.G., Holdnett, B.K., (2002) J. Phys. Chem. B, 106 (29), pp. 7340-7347; Macdonald, I.D.C., Smith, W.E., (1996) Langmuir, 12, p. 706; Wilson, K.P., Malcolm, B.A., Matthews, B.W., (1992) J. Biol. Chem., 267, p. 10842
Correspondence Address	Kovaleva, E.G.; Institute of Chemical Engineering, Ural Federal University, Mira St., 19, Russian Federation
Publisher	Elsevier
CODEN	MIMMF
Language of Original Document	English
Abbreviated Source Title	Microporous Mesoporous Mater.
Source	Scopus