The influence of the mixed H+-Na+ form of KB-2 carboxyl cationite and of pH within ionite grains on the state of Cu(II) ions and the catalytic properties of ionite catalysts containing Cu(II) / Kovaleva E.G., Molochnikov L.S., Lipunov I.N. // Russian Journal of Physical Chemistry A. - 2000. - V. 74, l. 8. - P. 1262-1267.

ISSN:

00360244

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Article

Abstract:

The state of Cu(II) ions in a KB-2 × 4 carboxyl cation exchanger in the initial mixed H+-Na+ form was studied depending on the content of the Na+ form, the amount of adsorbed Cu(II) ions, sample moisture content, and pH within ionite grains. Acidity of the ionite phase was found to play the key role in the formation of complexes having various compositions and in determining the catalytic properties of ionite catalysts containing Cu(II).

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0034336135&partnerID=40&md5=6d4c38525edea123f6e786f3dec38428
Affiliations	Ural State Forestry Academy, Russian Academy of Sciences, Sibirskii trakt 37, Yekaterinburg, 620032, Russian Federation
References	Molochnikov, L.S., Kovalyova, E.G., Grigor'ev, I.A., (1996) Metal-Containing Polymeric Materials, p. 395. , New York: Plenum; Molochnikov, L.S., Kovaleva, E.G., Lipunov, I.N., (1996) Zh. Fiz. Khim., 70 (11), p. 2091; Vishnevskaya, G.P., Safin, R.Sh., Kozyrev, B.M., (1974) Dokl. Akad. Nauk SSSR, 219 (2), p. 371; Vishnevskaya, G.P., Safin, R.Sh., Radionov, B.K., (1987) Vysokomol. Soedin., Ser. B, 29 (4), p. 247; Vishnevskaja, G.P., Saphin, R.Sh., Molotchnikov, L.S., (1977) Mol. Phys., 34 (5), p. 1329; Kazantsev, E.I., Pakholkov, V.S., Kokoshko, Z.Yu., (1969) Ionoobmennye Materialy, Ikh Sintez i Svoistva (Ion-Exchange Materials, Their Synthesis and Properties), , Sverdlovsk: Ural'sk. Politekhn. Inst; Polyanskii, N.G., Gorbunov, G.V., Polyanskaya, N.L., (1976) Melody Issledovaniya Ionitov (Methods for Studying Ion-Exchangers), , Moscow: Khimiya; Zhilenko, M.P., Rudenko, A.P., (1995) Vestn. Mosk. Univ., Ser. 2: Khim., 36 (3), p. 271; Khramtsov, V.V., Weiner, L.M., Grigor'ev, I.A., (1985) J. Magn. Reson., 61, p. 397; Fung Ti Shi, Astanina, A.N., Bystrov, T.S., (1984) Zh. Fiz. Khim., 58 (7), p. 1818; Efendiev, A.A., Shakhtakhtinskaya, A.T., (1978) Vysokomol. Soedin., Ser. A, 20 (2), p. 314; Leikin, Yu.A., Rotaichak, V., (1971) Khimiya i Tekhnologiya Vysokomolekulyarnykh Soedinenii (Chemistry and Technology of Macromolecular Compounds), 3, p. 86; Hoorn, H.J., (1996) Synthesis and Properties of Selective Chelating Ion Exchangers Based on Glycidyl Methacrylate Copolymers, , PhD Dissertation, Leiden; Kopylova, V.D., Astanina, A.N., (1987) Ionitnye Kompleksy v Katalize (Ion-Exchange Complexes in Catalysis), , Moscow: Khimiya
Correspondence Address	Kovaleva, E.G.; Ural State Forestry Academy, Russian Academy of Sciences, Sibirskii trakt 37, Yekaterinburg, 620032, Russian Federation
Language of Original Document	English
Abbreviated Source Title	Russ. J. Phys. Chem. A
Source	Scopus