Synthesis and catalytic properties of metal complexes with modified ionites / Lipunov I.N., Pervova I.G., Lipunova G.N., Molochnikov L.S., Kovaleva E.G. // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. - 1997. - V. 23, l. 12. - P. 877-880.

ISSN:
10703284
Type:
Article
Abstract:
The ionites were modified using novel sulfo-containing hetarylformazanes. The sorption properties of the modified ionites were studied, and their selectivity toward the Cu2+ ions was revealed. The EPR method was used to demonstrate that, regardless of the structures of the initial formazane group and polymer unit cell, the coordination core of the modified copper-containing ionites mainly has the CuN4 composition. The catalytic properties of the copper- and iron-containing polymeric formazanes of various structures were examined in the liquid-phase reactions of oxidation of sulfides and hydrogen sulfide. © 1997 MAEe cyrillic signK Hayκa/Interperiodica Publishing.
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References Yuffa, A.Ya., (1981) Geterogennye Metallokompleksnye Katalizatory (Heterogeneous Metallocomplex Catalysts), , Moscow: Khimiya; Pomogailo, A.D., (1988) Polimernye Immobilizovannye Metallokompleksnye Katalizatory (Polymeric Immobilized Metallocomplex Catalysts), , Moscow: Nauka; Buzykin, B.I., Lipunova, G.N., Sysoeva, L.P., Rusinova, L.I., (1992) Khimiya Formazanov (Chemistry of Formazanes), , Moscow: Nauka; Vishnevskaya, G.P., Molochnikov, L.S., Safin, R.Sh., (1992) EPR v Ionitakh (EPR of Ionites), , Moscow: Nauka; Kopylova, V.D., Astanina, A.N., (1987) Ionitnye Kompleksy v Katalize (Ionite Complexes in Catalysis), , Moscow: Khimiya; Shmelev, L.V., Lipunova, G.N., Kessenikh, A.V., (1993) Koord. Khim., 19 (3), p. 215; Shmelev, L.V., Pervova, I.G., Lipunova, G.N., (1993) Koord. Khim., 19 (12), p. 904; Fung, T.Sh., Astanina, A.N., Bystrov, T.S., (1984) Zh. Fiz. Khim., 58 (7), p. 1818; Astanina, A.N., Fung, T.Sh., Rudenko, A.P., (1983) Zh. Neorg. Khim., 28 (6), p. 1214; Müller, A., Brown, D., Lipunova, G., (1994) Naturwiss., (81), p. 136
CODEN RJCCE
Language of Original Document English
Abbreviated Source Title Russ. J. Coord. Chem.
Source Scopus