Reactions of 5-diazo-4-nitroimidazole with hydrochloric acid / Sadchikova E.V., Mokrushin V.S., Pospelova T.A., Selezneva I.S. // Chemistry of Heterocyclic Compounds. - 1999. - V. 35, l. 2. - P. 176-179.

ISSN:
00093122
Type:
Article
Abstract:
Reaction of 5-diazo-4-nitroimidazole with concentrated hydrochloric acid leads to 4-chloro-5-diazoimidazole. The same product is formed together with a small quantity of 5-chloro-4-nitroimidazole with 1 N hydrochloric acid, but with 0.1 N hydrochloric acid only chloronitroimidazole was isolated. The results obtained are explained with the aid of quantum chemical calculations. ©1999 KluwerAcademic/Plenum.
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Affiliations Urals State Technical University, Urals Polytechnical Institute (UPI), Ekaterinburg 620002, Russian Federation
References Mokrushin, V.S., Selezneva, I.S., Pospelova, T.A., Usova, V.K., (1997) Khim. Geterotsikl. Soedin., (9), p. 1245; Gehlen, H., Dost, J., (1963) Justus Liebigs Ann. Chem., 665, p. 144; Patai, S., (1978) Chemistry of Diazonium and Diazo Groups, p. 1099. , Interscience, Chichester, New York, Brisbane, Toronto; Oku, A., Matsui, A., (1979) J. Org. Chem., 44, p. 3342; Sharnin, G.P., Fassakhov, R.Kh., Eneikina, T.A., Orlov, P.P., (1977) Khim. Geterotsikl. Soedin., (5), p. 653; Mokrushin, V.S., Selezneva, I.S., Pospelova, T.A., Usova, V.K., Malinskaya, S.M., Anoshina, G.M., Zubova, T.E., Pushkareva, Z.V., (1982) Khim.-farm. Zh., (3), p. 303
Correspondence Address Sadchikova, E.V.; Urals State Technical University, Urals Polytechnical Institute (UPI), Ekaterinburg 620002, Russian Federation
CODEN CHCCA
Language of Original Document English
Abbreviated Source Title Chem. Heterocycl. Compd.
Source Scopus