Reactions of 4,5-dinitroimidazole and 4(5)-nitroimidazole-5(4)-sulfonic acid with nucleophiles / Mokrushin V.S., Belyaev N.A., Kolobov M.Yu., Fedotov A.N. // Chemistry of Heterocyclic Compounds. - 1983. - V. 19, l. 6. - P. 650-652.

ISSN:
00093122
Type:
Article
Abstract:
The reactions of 4,5-dinitroimidazole and 5(4)-nitroimidazole-4(5)-sulfonic acid with nucleophilic agents were studied. Mercapto-, alkoxy-, and aminonitroimidazoles were synthesized. In the reaction of dinitroimidazole with sodium alkoxides 5(4)-nitroimidazole was obtained in addition to alkoxynitroimidazoles. It is shown that in the formation of salts of the starting imidazoles with bases nucleophilic-substitution reactions take place only with "soft" reagents. © 1983 Plenum Publishing Corporation.
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DOI:
10.1007/BF00523079
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250146223&doi=10.1007%2fBF00523079&partnerID=40&md5=8e0c8d309142edcfd0d7fb7d94c37997
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250146223&doi=10.1007%2fBF00523079&partnerID=40&md5=8e0c8d309142edcfd0d7fb7d94c37997
Affiliations S. M. Kirov Ural Polytechnic Institute, Sverdlovsk, 620002, Russian Federation
References Kochergin, P.M., (1966) Khim. Geterotsikl. Soedin., 5, p. 749; Balaban, Y.E., XL.?An investigation into the formation of 4(5)-aminoglyoxalines. Part I (1930) Journal of the Chemical Society (Resumed), p. 268; Fargher, R.G., Ryman, F.L., (1919) J. Chem. Soc., 115, p. 217; Mokrushin, V.S., Selezneva, I.S., Pospelova, T.A., Usova, V.K., Malinskaya, S.A., Anoshina, G.M., Zubova, T. É., Pushkareva, Z.V., (1982) Khim.-farm. Zh., 3, p. 303
Correspondence Address Mokrushin, V.S.; S. M. Kirov Ural Polytechnic Institute, Sverdlovsk, 620002, Russian Federation
Publisher Kluwer Academic Publishers-Plenum Publishers
CODEN CHCCA
Language of Original Document English
Abbreviated Source Title Chem Heterocycl Compd
Source Scopus