Diaqua{[}N,N-di(2-carboxyethyl)-o-anisidinato]copper(II) dihydrate {[}Cu(o-Andp)(H2O)(2)] center dot 2H(2)O: Synthesis and crystal structure / Skorik YA,Romanenko GV,Neudachina LK,Vshivkov AA // RUSSIAN JOURNAL OF COORDINATION CHEMISTRY. - 2001. - V. 27, l. 11. - P. 796-802.

ISSN/EISSN:

1070-3284 / нет данных

Type:

Article

Abstract:

Crystals of {[}Cu(o-Andp)(H2O)(2)] . 2H(2)O (where o-Andp(2-) is o-anisidine-NN-di-3-propionate) were synthesized and studied using X-ray diffraction analysis. The crystals are triclinic: a = 12.063(1) Angstrom, b = 12.483(3) Angstrom, c = 13.586(2) Angstrom, alpha = 91.29(1)degrees, beta = 111.67(1)degrees, gamma = 104.00(1)degrees, V = 1830.5(5) Angstrom (3), space group P (1) over bar, Z = 2, and R = 0.0528 for 5965 reflections with 1 greater than or equal to 2 sigma (I). The two crystal lographically independent complexes are isostructural. The tetragonal-bipyramidal coordination of copper(III) involves three O atoms, the N atom of the tetradentate ligand o-Andp(2-), and two O atoms from water. The aminodipropionate group of the ligand (average Cu-O 1.939 Angstrom and Cu-N 2.051 Angstrom) and one of the coordinated water molecules (Cu-O(w) 1.991 Angstrom) lie in the equatorial plane. The second water molecule (Cu-O(w) 2.32 Angstrom) and the methoxy O atom of o-Andp(2-) (Cu-O 2.37 Angstrom) are in the apical positions of the bipyramid.

Author keywords:

MOLECULAR-STRUCTURE; PENTAHYDRATE; COMPLEXES; LIGANDS

DOI:

10.1023/A:1012519106613

Web of Science ID:

ISI:000172169900009

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	NOV
Publisher	MAIK NAUKA/INTERPERIODICA
Address	C/O KLUWER ACADEMIC-PLENUM PUBLISHERS, 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
Keywords-Plus	MOLECULAR-STRUCTURE; PENTAHYDRATE; COMPLEXES; LIGANDS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
ResearcherID-Numbers	Skorik, Yury/A-8128-2008
ORCID-Numbers	Romanenko, Galina/0000-0001-8852-2759
Number-of-Cited-References	18
Journal-ISO	Russ. J. Coord. Chem.
Doc-Delivery-Number	492LM