1,2,4-Triazine method of bipyridine ligand synthesis for the preparation of new luminescent Eu(III) complexes / Prokhorov Anton M.,Kozhevnikov Valery N.,Kopchuk Dmitry S.,Bernard Helene,Le Bris Nathalie,Tripier Raphael,Handel Henri,Koenig Burkhard,Kozhevnikov Dmitry N. // TETRAHEDRON. - 2011. - V. 67, l. 3. - P. 597-607.

ISSN/EISSN:

0040-4020 / нет данных

Type:

Article

Abstract:

The `triazine' methodology for the synthesis of functionalized bipyridine ligands proved to be a convenient method for the preparation of luminescent Eu(III) complexes. The approach allows flexible construction of chromophore and coordination sphere with control of photophysical properties. Europium (III) complexes {[}Eu1]-{[}Eu5] prepared in this way exhibit intense long-life metal-centered luminescence in aqueous media. The aromatic substituent in the position 5 of bipyridine has a significant influence on luminescence parameters and is used to introduce functionality for bioconjugation. The complexes {[}Eu4] and {[}Eu5] bearing primary amine groups are ready-to-go luminescent `tags' for peptide labeling. (C) 2010 Elsevier Ltd. All rights reserved.

Author keywords:

SIMPLE LEGO SYSTEM; DIELS-ALDER; CYCLOADDITION PATHWAY; CONTRAST AGENTS; EUROPIUM; TERBIUM; 2,2'-BIPYRIDINE; PLATINUM(II); PYRIDINES

DOI:

10.1016/j.tet.2010.11.058

Web of Science ID:

ISI:000286862900005

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JAN 21
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Keywords-Plus	SIMPLE LEGO SYSTEM; DIELS-ALDER; CYCLOADDITION PATHWAY; CONTRAST AGENTS; EUROPIUM; TERBIUM; 2,2'-BIPYRIDINE; PLATINUM(II); PYRIDINES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	aprohor@yandex.ru
ResearcherID-Numbers	Kozhevnikov, Valery/B-1178-2010 Prokhorov, Anton/B-9789-2011 Koenig, Burkhard/A-1362-2009
ORCID-Numbers	Kozhevnikov, Valery/0000-0001-7032-8886 Koenig, Burkhard/0000-0002-6131-4850
Funding-Acknowledgement	Russian Foundation for Basic Research {[}08-03-00585-a]
Funding-Text	This work was supported by Russian Foundation for Basic Research (grant 08-03-00585-a).
Number-of-Cited-References	35
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	21
Journal-ISO	Tetrahedron
Doc-Delivery-Number	715EI