2,2 `-Bipyridinyl carboranes as B,N,N-ligands in cyclometallated complexes of platinum(II) / Prokhorov Anton M.,Slepukhin Pavel A.,Rusinov Vladimir L.,Kalinin Valery N.,Kozhevnikov Dmitry N. // CHEMICAL COMMUNICATIONS. - 2011. - V. 47, l. 27. - P. 7713-7715.

ISSN/EISSN:

1359-7345 / нет данных

Type:

Article

Abstract:

Novel B,N,N-cyclometallated Pt-II complexes of 2,2'-bipyridin-6-yl carboranes exhibit absorption and emission similar to relative Pt-II complexes of aromatic C,N,N-ligands: the same transitions but lower intensities. DFT calculations suggest the former emits from the (MLCT)-M-3 state while for the latter the mixed (ICT)-I-3-MLCT transitions should be considered.

Author keywords:

O-CARBORANE; METALLACARBORANES; PHOTOLUMINESCENT; CHEMISTRY; CRYSTAL; LIGANDS

DOI:

10.1039/c1cc12230d

Web of Science ID:

ISI:000292113700041

Соавторы в МНС:

Другие поля

Поле	Значение
Publisher	ROYAL SOC CHEMISTRY
Address	THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Language	English
Keywords-Plus	O-CARBORANE; METALLACARBORANES; PHOTOLUMINESCENT; CHEMISTRY; CRYSTAL; LIGANDS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	aprohor@yandex.ru dnk@ios.uran.ru
ResearcherID-Numbers	Prokhorov, Anton/B-9789-2011
Funding-Acknowledgement	Russian Foundation for Basic Research; Ural Federal University
Funding-Text	We thanks the Russian Foundation for Basic Research and Ural Federal University for support.
Number-of-Cited-References	26
Usage-Count-Since-2013	15
Journal-ISO	Chem. Commun.
Doc-Delivery-Number	783WB