Synthesis, Crystal Structure and Biological Activity of N'-tert-butyl-N-(3-methoxylbenzoyl)-N-(4-methyl-1,2,3-thiadiazole-5-form ylhydrazine / Huang Jie,Wang Huan,Fan Zhi-Jin,Song Hai-Bin,Zhao Hui,Huang Yun,Prokhorova Polina E.,Belskaya Nataliya P.,Morzherin Yury Yu.,Bakulev Vasiliy A. // JOURNAL OF CHEMICAL CRYSTALLOGRAPHY. - 2011. - V. 41, l. 12. - P. 1860-1865.

ISSN/EISSN:

1074-1542 / нет данных

Type:

Article

Abstract:

The title compound, N'-tert-butyl-N-(3-methoxylbenzoyl)-N-(4-methyl-1,2,3-thiadiazole-5-form ylhydrazine (C(16)H(20)N(4)O(3)S) was prepared from the reaction of 4-methyl-1,2,3-thiadiazole-5-carbonyl chloride with N'-tert-Butyl-3-methoxylbenzohydrazine, and its structure was characterized by (1)Hydrogen Nuclear Magnetic Resonance, High-Resolution Mass Spectrometry, IR spectra, and single crystal X-ray diffraction. The crystal of the title compound belongs to monoclinic system, space group P 21/c with cell parameters a = 17.986(2) , b = 8.0180(10) , c = 12.0190(14) , alpha = 90A degrees, beta = 91.160(5)A degrees, gamma = 90A degrees, V = 1732.9(4) (3), Z = 4, D (c) = 1.335 g/cm(3), mu (Mo Ka) = 0.209 mm(-1), F (000) = 736, R = 0.0367 and wR = 0.0932. X-ray diffraction analysis indicates that all rings in the title compound are non-planar. The bioassay results indicated that, the title compound had good fungicide activity against Sclerotinia sclerotiorum, certain extent of insecticidal activity against Plutella xylostella L.

Author keywords:

X-ray diffraction; Single crystal structure; Synthesis; Diacylhydrazine; Biological activity NONSTEROIDAL ECDYSONE AGONIST; INSECTICIDAL ACTIVITY; 1,2,3-THIADIAZOLE DERIVATIVES; ANALOGS; RESISTANCE; DESIGN

DOI:

10.1007/s10870-011-0189-1

Web of Science ID:

ISI:000296883100012

Соавторы в МНС:

Другие поля

Поле	Значение
Month	DEC
Publisher	SPRINGER/PLENUM PUBLISHERS
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	NONSTEROIDAL ECDYSONE AGONIST; INSECTICIDAL ACTIVITY; 1,2,3-THIADIAZOLE DERIVATIVES; ANALOGS; RESISTANCE; DESIGN
Research-Areas	Crystallography; Spectroscopy
Web-of-Science-Categories	Crystallography; Spectroscopy
Author-Email	5787huangyun@sina.com
ResearcherID-Numbers	G, Neela/H-3016-2014 Belskaya, Nataliya/S-3953-2017 Morzherin, Yury/M-7420-2013
ORCID-Numbers	Belskaya, Nataliya/0000-0002-2509-7916 Morzherin, Yury/0000-0002-1333-6676
Funding-Acknowledgement	National Natural Science Foundation of China {[}20872071, 20911120069]; Natural Science Foundation of Tianjin {[}10JCZDJC17500]; National Key Project for Basic Research {[}2010CB126105]; National Key Technology Research and Development Program {[}2011BAE06B02, 2011BAE06B05]; Foundation of Achievements Transformation and Spreading of Tianjin Agricultural Science and Technology {[}201002250]; Common Wealth Specialized Research Fund of China Agriculture {[}nyhyzx3-21, 201103016, 201003029]; Russian Foundation for Basic Research {[}RFBR 08-03-00376a, RFBR/NNSF 08-03-92208 a]
Funding-Text	This study was funded in part by grants from the National Natural Science Foundation of China (Nos. 20872071 and 20911120069), the Natural Science Foundation of Tianjin (10JCZDJC17500), the National Key Project for Basic Research (2010CB126105), National Key Technology Research and Development Program (2011BAE06B02 and 2011BAE06B05) and the Foundation of Achievements Transformation and Spreading of Tianjin Agricultural Science and Technology (201002250); The Common Wealth Specialized Research Fund of China Agriculture (nyhyzx3-21, 201103016 and 201003029), and the Russian Foundation for Basic Research (Grant Numbers RFBR 08-03-00376a and RFBR/NNSF 08-03-92208 a).
Number-of-Cited-References	28
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	20
Journal-ISO	J. Chem. Crystallogr.
Doc-Delivery-Number	846FR