3-(4-Thiocarbamoyl-1,2,3-triazol-1-yl)benzo-15-crown-5: synthesis and properties / Prokhorova P. E.,Glukhareva T. V.,Dyudya L. V.,Alekseeva E. A.,Morzherin Yu. Yu. // RUSSIAN CHEMICAL BULLETIN. - 2010. - V. 59, l. 4. - P. 867-869.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

A reaction of 1,2,3-thiadiazole-4-carbaldehyde with 3-aminobenzo-15-crown-5 involves the Cornforth rearrangement of the 1,2,3-thiadiazole ring, which leads to 1,2,3-triazole-4-carbothioamide containing the benzocrown ether substituent in position 1 of the triazole ring. Reversible formation of the isomeric thiadiazole occurs in aprotic nonpolar solvents such as deuterated chloroform. These compounds are suitable for extraction of alpha-amino acids from an aqueous phase.

Author keywords:

rearrangement; nitrogen-containing heterocycles; crown ether; extraction; alpha-amino acids RECEPTORS

DOI:

10.1007/s11172-010-0177-1

Web of Science ID:

ISI:000283302000033

Соавторы в МНС:

Другие поля

Поле	Значение
Month	APR
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	RECEPTORS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	Alyeksyeyeva@rambler.ru morzherin@mail.ru
ResearcherID-Numbers	Morzherin, Yury/M-7420-2013 Glukhareva, Tatiana/A-4610-2016
ORCID-Numbers	Morzherin, Yury/0000-0002-1333-6676 Glukhareva, Tatiana/0000-0002-5231-9879
Funding-Acknowledgement	Russian Foundation for Basic Research {[}07-03-96119]
Funding-Text	This work was financially supported by the Russian Foundation for Basic Research (Project No. 07-03-96119).
Number-of-Cited-References	8
Usage-Count-Since-2013	10
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	668VY