A tandem of the Cornforth rearrangements of 4-(1,2,3-triazol-1-yl)iminomethyl-1,2,3-thiadiazole / Glukhareva TV,Morzherin YY,Savel'eva EA,Rozin YA,Tkachev AV,Bakulev VA // RUSSIAN CHEMICAL BULLETIN. - 2001. - V. 50, l. 2. - P. 268-271.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The method for the synthesis of 5-(2,6-dimethylmorpholino)-1,2,3-thiadiazole-4-carbaldehyde was proposed. Its reaction with sodium 1-amino-4-(N-methyl)carbamoyl- 1,2,3-triazol-5-olate proceeds through a tandem of the Cornforth rearrangements. The initially formed azomethine isomerizes into sodium 4'-(2,6-dimethylmorpholino)thiocarbonyl-4-(N-methyl)carbamoyl- 1,1'-bis{[}1,2,3]triazolyl-5-olate, which then rearranges to give sodium 4-\{N-\{4-(2,6-dimethylmorpholinothiocarbonyl)-1,2,3-triazol-1-yl]carbam oyl\}-1-methyl-1,2,3-triazol-5-olate.

Author keywords:

Cornforth rearrangement; diazomalonamide; 1,2,3-thiadiazole; 1,2,3-triazole MOLECULAR-REARRANGEMENTS

DOI:

10.1023/A:1009582402351

Web of Science ID:

ISI:000173636600018

Соавторы в МНС:

Другие поля

Поле	Значение
Month	FEB
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	MOLECULAR-REARRANGEMENTS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	morjerine@htf.ustu.ru atkachev@nioch.nsc.ru
ResearcherID-Numbers	Morzherin, Yury/M-7420-2013 Glukhareva, Tatiana/A-4610-2016
ORCID-Numbers	Morzherin, Yury/0000-0002-1333-6676 Glukhareva, Tatiana/0000-0002-5231-9879
Number-of-Cited-References	15
Usage-Count-Last-180-days	4
Usage-Count-Since-2013	10
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	517XW