STUDY OF POLYFUNCTIONAL DIAZO-COMPOUNDS REACTIVITY IN HETEROCYCLIZATION BY THE METHOD OF INTRAMOLECULAR COMPETITIVE REACTIONS / BAKULEV VA,MORZHERIN YY,LEBEDEV AT,DANKOVA EF,KOLOBOV MY,SHAFRAN YM // BULLETIN DES SOCIETES CHIMIQUES BELGES. - 1993. - V. 102, l. 7. - P. 493-502.

ISSN/EISSN:

0037-9646 / нет данных

Type:

Article

Abstract:

New method for the study of reactivity of highly reactive compounds was proposed and applied to determine the effect of substituents in alpha-diazoacetamidines, and -imidates. The introduction of electron-releasing groups to the nitrogen atom of the amidine, and imidate functions was shown to increase the reactivity of the substances studied. The results obtained are in good agreement with the heteroelectrocyclic mechanism suggested for the cyclization of these compounds.

Author keywords:

CYCLIZATION; CHEMISTRY

DOI:

нет данных

Web of Science ID:

ISI:A1993MF41600007

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUL
Publisher	SOC CHIMIQUE BELGIQUE
Address	OFFICE INT DE LIBRAIRIE 30 AVE MARNIX, B-1050 BRUSSELS, BELGIUM
Language	English
Keywords-Plus	CYCLIZATION; CHEMISTRY
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
ResearcherID-Numbers	Morzherin, Yury/M-7420-2013
ORCID-Numbers	Morzherin, Yury/0000-0002-1333-6676
Number-of-Cited-References	19
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	3
Journal-ISO	Bull. Soc. Chim. Belg.
Doc-Delivery-Number	MF416