Mass spectrometric studies of self-condensation products of cyclohexanone under alkaline conditions and synthesis of dodecahydrotriphenylene and triphenylene from easily available reactants / Kovalev I. S.,Kopchuk D. S.,Zyryanov G. V.,Khasanov A. F.,Rusinov V. L.,Chupakhin O. N. // RUSSIAN CHEMICAL BULLETIN. - 2014. - V. 63, l. 7. - P. 1539-1542.

ISSN/EISSN:
1066-5285 / 1573-9171
Type:
Article
Abstract:
LC-MS was used to study products of cyclohexanone self-condensation under alkaline conditions. Improved methods (as compared to those described in the literature) for the preparation of dodecahydrotriphenylene and highly pure sublimed triphenylene were suggested based on the easily available and cheap reactants. Possible reasons of the low yield of the target dodecahydrotriphenylene in the step of oligomerization of cyclohexanone were identified.
Author keywords:
triphenylene; cyclohexanone; trimerization; aromatization EFFICIENT SYNTHESIS; COUPLING REACTIONS; HYDROCARBONS; EQUIVALENTS; NICKEL
DOI:
нет данных
Web of Science ID:
ISI:000350878300012
Соавторы в МНС:
Другие поля
Поле Значение
Month JUL
Publisher SPRINGER
Address 233 SPRING ST, NEW YORK, NY 10013 USA
Language English
EISSN 1573-9171
Keywords-Plus EFFICIENT SYNTHESIS; COUPLING REACTIONS; HYDROCARBONS; EQUIVALENTS; NICKEL
Research-Areas Chemistry
Web-of-Science-Categories Chemistry, Multidisciplinary
Author-Email gvzyryanov@gmail.com chupakhin@ios.uran.ru
Funding-Acknowledgement Ministry of Education and Science of the Russian Federation {[}14.A18.21.0817]; Russian Federation {[}MK-1511.2013.3]; Government of the Russian Federation {[}02.A03.21.0006]
Funding-Text This work was financially supported by the Ministry of Education and Science of the Russian Federation (State Contract No. 14.A18.21.0817), the Council on Grants at the President of the Russian Federation (Program of State Support for Young Scientists-Candidates of Science (Grant MK-1511.2013.3), and the Government of the Russian Federation (Program 211, Agreement No. 02.A03.21.0006).
Number-of-Cited-References 26
Usage-Count-Last-180-days 1
Usage-Count-Since-2013 6
Journal-ISO Russ. Chem. Bull.
Doc-Delivery-Number CD2BJ