Asymmetric induction in the reactions of azinones with C-nucleophiles / Chupakhin O. N.,Egorov I. N.,Rusinov V. L.,Slepukhin P. A. // RUSSIAN CHEMICAL BULLETIN. - 2010. - V. 59, l. 5. - P. 991-1001.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

Effect of acylating agents on the course of addition of C-nucleophiles to 1,2,4- and 1,3,5-triazinones, as well as to quinoxalin-2(1H)-one, was studied. A series of new azinone derivatives was obtained. A method for the preparation of diastereomerically pure addition products of indoles to 1,2,4-triazinones and quinoxalin-2(1H)-one in the presence of N-Ts-L-amino acid acyl chlorides was suggested.

Author keywords:

triazinones; 1,2,4-triazin-5(4H)-one; 1,2,4-triazin-3(2H)-one; 1,3,5-triazin-2,4(1H,3H)-one; quinoxalin-2(1H) -one; diastereoselective synthesis; aromatic nucleophilic; addition; C-nucleophiles; amino BIFUNCTIONAL CATALYST; EFFICIENT SYNTHESIS

DOI:

10.1007/s11172-010-0195-z

Web of Science ID:

ISI:000284320500017

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAY
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	BIFUNCTIONAL CATALYST; EFFICIENT SYNTHESIS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	chupakhin@ios.uran.ru i.n.egorov@gmail.com
Funding-Acknowledgement	Ministry of Science and Education of the Russian Federation {[}02.512.11.2237]
Funding-Text	This work was financially supported by the Ministry of Science and Education of the Russian Federation (State Contract 02.512.11.2237).
Number-of-Cited-References	20
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	2
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	681MS