Stable sigma(H)-adducts in reactions of ferrocenyllithium with azines / Utepova I. A.,Lakhina A. E.,Varaksin M. V.,Kovalev I. S.,Rusinov V. L.,Slepukhin P. A.,Kodess M. I.,Chupakhin O. N. // RUSSIAN CHEMICAL BULLETIN. - 2008. - V. 57, l. 10. - P. 2156-2161.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

Stable sigma(H)-adducts as intermediates of the nucleophilic substitution of hydrogen in 3-(2-pyridyl)-1,2,4-triazines were obtained for the first time using ferrocenyllithium as a nucleophilic reagent. The three-dimensional structures of the reaction products were established based on the X-ray diffraction study of 1-{[}4-ethyl-6-phenyl-3-(2-pyridyl)-5(H)-1,2,4-triazin-5-yl]ferrocene.

Author keywords:

ferrocene; 1,2,4-triazines; sigma(H)-adducts; nucleophilic substitution of hydrogen (S-N(H)); C-C coupling STRUCTURAL-CHARACTERIZATION; MOLECULAR-STRUCTURE; METAL-COMPLEXES; LIGANDS; COORDINATION; DERIVATIVES; 4'-FERROCENYL-2,2'/6',2''-TERPYRIDINE; SUBSTITUTION; SPECTROSCOPY; CRYSTAL

DOI:

10.1007/s11172-008-0292-4

Web of Science ID:

ISI:000270586500016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	STRUCTURAL-CHARACTERIZATION; MOLECULAR-STRUCTURE; METAL-COMPLEXES; LIGANDS; COORDINATION; DERIVATIVES; 4'-FERROCENYL-2,2'/6',2''-TERPYRIDINE; SUBSTITUTION; SPECTROSCOPY; CRYSTAL
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	rusinov@mail.ustu.ru chupakhin@ios.uran.ru
ResearcherID-Numbers	Varaksin, Mikhail/J-5007-2015
ORCID-Numbers	Varaksin, Mikhail/0000-0002-7997-3686
Funding-Acknowledgement	Russian Foundation for Basic Research {[}07-03-96104r\_Ural\_a, 06-03-32764]; President of the Russian Federation {[}NSh-3758.2008.3]
Funding-Text	This study was financially supported by the Russian Foundation for Basic Research (Project Nos 07-03-96104r\_Ural\_a and 06-03-32764) and the Council on Grants of the President of the Russian Federation (Program for State Support of Leading Scientific Schools of the Russian Federation, Grant NSh-3758.2008.3).
Number-of-Cited-References	38
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	11
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	504AZ