Synthesis of functionalized fluorescent europium(III) terpyridyl chelates / Kozhevnikov VN,Kozhevnikov DN,Rusinov VL,Chupakhin ON,Konig B // SYNTHESIS-STUTTGART. - 2003. - V. , l. 15. - P. 2400-2404.

ISSN/EISSN:

0039-7881 / нет данных

Type:

Article

Abstract:

The synthesis of substituted terpyridines via triazine intermediates is described. The intermediates allow the facile introduction of cyano groups, which are converted into amino diacetic acid moieties. Together with the terpyridine nitrogen atoms they shield coordinated europium(III) ions completely from the solvent. The terpyridines may be further functionalized for specific applications using ligands, bromo substituents, and standard transition metal mediated coupling methods. This makes the title compounds valuable intermediates for the preparation of luminescent probes in biochemistry, medicinal diagnostics or materials science.

Author keywords:

heterocycles; pyridines; diels-alder reaction; ligands; lanthanide TIME-RESOLVED FLUORESCENCE; VERSATILE STRATEGY; LUMINESCENCE; TERBIUM(III); COMPLEXES; BINDING; SYSTEMS; ASSAYS; METAL

DOI:

10.1055/s-2003-41071

Web of Science ID:

ISI:000186451000027

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT 31
Publisher	GEORG THIEME VERLAG KG
Address	RUDIGERSTR 14, D-70469 STUTTGART, GERMANY
Language	English
Keywords-Plus	TIME-RESOLVED FLUORESCENCE; VERSATILE STRATEGY; LUMINESCENCE; TERBIUM(III); COMPLEXES; BINDING; SYSTEMS; ASSAYS; METAL
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	kozhevnikov\_v@htf.ustu.ru
ResearcherID-Numbers	Koenig, Burkhard/A-1362-2009 Kozhevnikov, Valery/B-1178-2010
ORCID-Numbers	Koenig, Burkhard/0000-0002-6131-4850 Kozhevnikov, Valery/0000-0001-7032-8886
Number-of-Cited-References	19
Usage-Count-Since-2013	10
Journal-ISO	Synthesis
Doc-Delivery-Number	741GU