Phase transitions in solutions of polystyrene with poly(methyl methacrylate) and polybutadiene under deformation / Rusinova E. V.,Adamova L. V.,Vshivkov S. A. // POLYMER SCIENCE SERIES A. - 2006. - V. 48, l. 2. - P. 159-163.

ISSN/EISSN:
0965-545X / нет данных
Type:
Article
Abstract:
By the cloud point and static sorption methods, phase diagrams are constructed and the concentration and temperature dependences of the Gibbs free energy of mixing and the interaction parameter are determined under static conditions and in a shear field for the poly( methyl methacrylate)-polystyrene-ethyl acetate, polystyrene-polybutadiene-toluene, polystyrene-polybutadiene, poly( methyl methacrylate)-polystyrene, poly( methyl methacrylate)-ethyl acetate, and polystyrene-ethyl acetate systems. Phase separation in the systems both under heating and cooling, as well as coexistence of three phases, is observed in the polystyrene poly( methyl methacrylate)-ethyl acetate system. Deformation changes the phase separation temperature by 30-40 K.
Author keywords:
MULTICOMPONENT POLYMER SOLUTIONS; SEPARATION; SYSTEM; SOLVENT; BLENDS; PARAMETER
DOI:
10.1134/S0965545X0602009X
Web of Science ID:
ISI:000245654000009
Соавторы в МНС:
Другие поля
Поле Значение
Month FEB
Publisher MAIK NAUKA/INTERPERIODICA/SPRINGER
Address 233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language English
Keywords-Plus MULTICOMPONENT POLYMER SOLUTIONS; SEPARATION; SYSTEM; SOLVENT; BLENDS; PARAMETER
Research-Areas Polymer Science
Web-of-Science-Categories Polymer Science
Author-Email Elena.rusinova@usu.ru
Number-of-Cited-References 25
Usage-Count-Since-2013 4
Journal-ISO Polym. Sci. Ser. A
Doc-Delivery-Number 156MR