Phase transitions in polymethylmethacrylate solutions / Vshivkov SA,Rusinova EV // VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A \& SERIYA B. - 1996. - V. 38, l. 10. - P. 1746-1750.

ISSN/EISSN:

0507-5475 / нет данных

Type:

Article

Abstract:

The temperature-concentration boundaries of the amorphous PMMA-solvent systems (with n-butanol, n-hexanol, acetonitrile, and ethyl acetate) were determined from experimental data and compared with the critical parameters calculated within the framework of the Flory and Prigogine- Patterson theories. The phase transitions in PMMA solutions exhibit certain features (unusual shapes of the boundary curves, phase separation for the positive values of secondary virial coefficients, impossibility to reach high degrees of solution supercooling), which are interpreted on the basis of data concerning the formation of macromolecular stereocomplexes in the systems studied.

Author keywords:

POLY(METHYL METHACRYLATE); STEREOCOMPLEX

DOI:

нет данных

Web of Science ID:

ISI:A1996VZ46600018

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT
Publisher	MEZHDUNARODNAYA KNIGA
Address	39 DIMITROVA UL., 113095 MOSCOW, RUSSIA
Language	Russian
Keywords-Plus	POLY(METHYL METHACRYLATE); STEREOCOMPLEX
Research-Areas	Polymer Science
Web-of-Science-Categories	Polymer Science
Number-of-Cited-References	35
Usage-Count-Since-2013	1
Journal-ISO	Vysokomol. Soedin.
Doc-Delivery-Number	VZ466