A novel synthesis of gamma-nitro ketones via detrifluoroacetylative Michael addition of 1-trifluoromethy1-1,3-diketones to conjugated nitroalkenes / Barkov Alexey Yu,Korotaev Vladislav Yu,Sosnovskikh Vyacheslav Ya // TETRAHEDRON LETTERS. - 2013. - V. 54, l. 50. - P. 6819-6821.

ISSN/EISSN:

0040-4039 / нет данных

Type:

Article

Abstract:

A novel synthesis of gamma-nitro ketones via detrifluoroacetylative Michael addition of 1-trifluoromethyl-1,3-diketones to conjugated nitroalkenes in the presence of sodium acetate in ethanol at room temperature is developed. A series of trifluoromethylated 1,3-diones and nitroalkenes are surveyed to determine the scope of this high-yielding reaction. (C) 2013 Elsevier Ltd. All rights reserved.

Author keywords:

1-Trifluoromethyl-1,3-diketones; Michael addition; Nitroalkenes; gamma-Nitro ketones; Detrifluoroacetylation 1,3-DICARBONYL COMPOUNDS; 3-COMPONENT CONDENSATION; TANDEM REACTION; BUILDING-BLOCK; CATALYST-FREE; DERIVATIVES; SOLVENT; 3,3,3-TRICHLORO(TRIFLUORO)-1-NITROPROPENES; 3,3,3-TRIFLUORO-1-NITROPROPENE; CYCLOHEXANE-1,3-DIONES

DOI:

10.1016/j.tetlet.2013.10.008

Web of Science ID:

ISI:000327285300006

Соавторы в МНС:

Другие поля

Поле	Значение
Month	DEC 11
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Keywords-Plus	1,3-DICARBONYL COMPOUNDS; 3-COMPONENT CONDENSATION; TANDEM REACTION; BUILDING-BLOCK; CATALYST-FREE; DERIVATIVES; SOLVENT; 3,3,3-TRICHLORO(TRIFLUORO)-1-NITROPROPENES; 3,3,3-TRIFLUORO-1-NITROPROPENE; CYCLOHEXANE-1,3-DIONES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	vyacheslav.sosnovskikh@usu.ru
ResearcherID-Numbers	Korotaev, Vladislav/L-2692-2016
ORCID-Numbers	Korotaev, Vladislav/0000-0002-7492-5116
Funding-Acknowledgement	Russian Foundation for Basic Research {[}11-03-00126]
Funding-Text	This work was supported financially by the Russian Foundation for Basic Research (Grant 11-03-00126).
Number-of-Cited-References	56
Usage-Count-Since-2013	15
Journal-ISO	Tetrahedron Lett.
Doc-Delivery-Number	256BS