Reaction of (E)-1,1,1-trichloro-3-nitrobut-2-ene with amines: diastereoselective synthesis of N-substituted alpha-trichloromethyl-beta-nitroamines / Barkov A. Yu.,Korotaev V. Yu.,Slepukhin P. A.,Kodess M. I.,Sosnovskikh V. Ya. // RUSSIAN CHEMICAL BULLETIN. - 2012. - V. 61, l. 8. - P. 1564-1569.

ISSN/EISSN:

1066-5285 / нет данных

Type:

Article

Abstract:

The addition of primary and secondary amines to (E)-1,1,1-trichloro-3-nitrobut-2-ene proceeded diastereoselectively and led to a number of new N-substituted alpha-trichloromethyl-beta-nitroamines, whose stereochemistry was confirmed by X-ray crystallography and NMR spectroscopy.

Author keywords:

nitroalkenes; amines; Michael reaction; beta-nitroamines; configurations; conformations; X-ray diffraction studies UBER ALIPHATISCHE NITROVERBINDUNGEN; NITROOLEFINEN

DOI:

10.1007/s11172-012-0207-2

Web of Science ID:

ISI:000321772100010

Соавторы в МНС:

Другие поля

Поле	Значение
Month	AUG
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
Keywords-Plus	UBER ALIPHATISCHE NITROVERBINDUNGEN; NITROOLEFINEN
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	Vladislav.Korotaev@usu.ru
ResearcherID-Numbers	Korotaev, Vladislav/L-2692-2016
ORCID-Numbers	Korotaev, Vladislav/0000-0002-7492-5116
Funding-Acknowledgement	Russian Foundation for Basic Research {[}11-03-00126]
Funding-Text	This work was financially supported by the Russian Foundation for Basic Research (Project No. 11-03-00126).
Number-of-Cited-References	22
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	7
Journal-ISO	Russ. Chem. Bull.
Doc-Delivery-Number	182VE