Three-component synthesis of substituted beta-(trifluoromethyl)pyrroles via Grob cyclization of 1,1,1-trifluoro-3-nitrobut-2-ene with 1,3-dicarbonylic compounds and ammonia or primary amines / Korotaev Vladislav Yu.,Barkov Alexey Yu.,Kotovich Ivan V.,Sosnovskikh Vyacheslav Ya. // JOURNAL OF FLUORINE CHEMISTRY. - 2012. - V. 138, l. . - P. 42-47.

ISSN/EISSN:

0022-1139 / нет данных

Type:

Article

Abstract:

A variety of substituted beta-(trifluoromethyl)pyrroles were easily synthesized in good yields by a one-pot, three-component Grob cyclization of 1,1,1-trifluoro-3-nitrobut-2-ene with 1,3-dicarbonyls (ethyl acetoacetate, acetylacetone, benzoylacetone) and ammonia or primary aliphatic amines. (C) 2012 Elsevier B.V. All rights reserved.

Author keywords:

alpha-(Trifluoroethylidene)nitroethane; 1,3-Dicarbonyls; Primary amines; Three-component reaction; Grob cyclization; alpha-(Trifluoromethyl)pyrroles PENTACYCLIC LAMELLARIN SKELETON; CONVENIENT SYNTHESIS; NITRO-OLEFINS; ACID-ESTERS; PYRROLES; FACILE; DERIVATIVES; TRIFLUOROMETHYLPYRROLES; HETEROCYCLES; 3-NITRO-2-(TRIFLUOROMETHYL)-2H-CHROMENES

DOI:

10.1016/j.jfluchem.2012.03.012

Web of Science ID:

ISI:000304691300005

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	ELSEVIER SCIENCE SA
Address	PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Language	English
Keywords-Plus	PENTACYCLIC LAMELLARIN SKELETON; CONVENIENT SYNTHESIS; NITRO-OLEFINS; ACID-ESTERS; PYRROLES; FACILE; DERIVATIVES; TRIFLUOROMETHYLPYRROLES; HETEROCYCLES; 3-NITRO-2-(TRIFLUOROMETHYL)-2H-CHROMENES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Author-Email	Vyacheslav.Sosnovskikh@usu.ru
ResearcherID-Numbers	Korotaev, Vladislav/L-2692-2016
ORCID-Numbers	Korotaev, Vladislav/0000-0002-7492-5116
Funding-Acknowledgement	Russian Foundation for Basic Research {[}11-03-00126-a]
Funding-Text	This work was financially supported by the Russian Foundation for Basic Research (Grant 11-03-00126-a).
Number-of-Cited-References	52
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	27
Journal-ISO	J. Fluor. Chem.
Doc-Delivery-Number	950ZV