Stereoselective tandem {[}4+2]/{[}3+2] cycloaddition reactions of 3,3,3-trichloro(trifluoro)-1-nitropropenes and 2,3-dihydrofuran / Korotaev Vladislav Yu.,Sosnovskikh Vyacheslav Ya.,Barabanov Mikhail A.,Barkov Alexey Yu.,Kodess Mikhail I. // MENDELEEV COMMUNICATIONS. - 2010. - V. 20, l. 1. - P. 17-19.

ISSN/EISSN:

0959-9436 / нет данных

Type:

Article

Abstract:

The first example of the domino hetero-Diels-Alder/1,3-dipolar cycloaddition, in which 3,3,3-trichloro(trifluoro)-1-nitropropenes act as both the heterodiene and the dipolarophile in the reaction with 2,3-dihydrofuran, is described. The trichloromethylated nitroolefin gave tricyclic nitroso acetal as a single regio- and stereoisomer, while the trifluoromethylated derivative afforded a 3:1 mixture of two regioisomeric cycloadducts.

Author keywords:

1,1,1-TRICHLORO-3-NITROPROPENE; NITROALKENES; DERIVATIVES

DOI:

10.1016/j.mencom.2010.01.007

Web of Science ID:

ISI:000274775000007

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JAN-FEB
Publisher	ELSEVIER SCIENCE BV
Address	PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Language	English
Keywords-Plus	1,1,1-TRICHLORO-3-NITROPROPENE; NITROALKENES; DERIVATIVES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	vyacheslav.sosnovskikh@usu.ru
ResearcherID-Numbers	Korotaev, Vladislav/L-2692-2016
ORCID-Numbers	Korotaev, Vladislav/0000-0002-7492-5116
Funding-Acknowledgement	Russian Foundation for Basic Research {[}06-03-04004]
Funding-Text	This study was supported by the Russian Foundation for Basic Research (grant no. 06-03-04004).
Number-of-Cited-References	22
Usage-Count-Since-2013	10
Journal-ISO	Mendeleev Commun.
Doc-Delivery-Number	558VC