Metal and Boron Derivatives of Fluorinated Cyclic 1,3-Dicarbonyl Compounds / Sevenard Dmitri V.,Khomutov Oleg G.,Boltachova Nadezhda S.,Filyakova Vera I.,Vogel Vera,Lork Enno,Sosnovskikh Vyacheslav Ya.,Iaroshenko Viktor O.,Roschenthaler Gerd-Volker // ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. - 2009. - V. 64, l. 5. - P. 541-550.

ISSN/EISSN:

0932-0776 / нет данных

Type:

Article

Abstract:

Starting from the corresponding cyclic 1,3-diketones or other precursors (cyclic ketones as well as lactones), several new salts and chelate complexes of fluorinated 1,3-dicarbonyls were obtained, Their preparative significance was demonstrated by straightforward syntheses of fluorinated pyrazoles, benzimidazoles and 1,7-ketoesters. The structure of a boron chelate of 2-(trifluoroacetyl)cyclohexanone was investigated by X-ray diffraction.

Author keywords:

Organofluorine Compounds; 1,3-Dicarbonyl Compounds; Salts; Chelates; Synthetic Application MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; COPPER(II) COMPLEXES; BETA-DIKETONES; 1,3-DIKETONES; ACIDS; 2-POLYFLUOROACYLCYCLOALKANONES; DIFLUORIDE; CHEMISTRY; REAGENTS

DOI:

нет данных

Web of Science ID:

ISI:000266467900010

Соавторы в МНС:

Другие поля

Поле	Значение
Month	MAY
Publisher	VERLAG Z NATURFORSCH
Address	POSTFACH 2645, 72016 TUBINGEN, GERMANY
Language	English
Keywords-Plus	MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; COPPER(II) COMPLEXES; BETA-DIKETONES; 1,3-DIKETONES; ACIDS; 2-POLYFLUOROACYLCYCLOALKANONES; DIFLUORIDE; CHEMISTRY; REAGENTS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear; Chemistry, Organic
Author-Email	sevenard@hfc-chemicals.com
Number-of-Cited-References	64
Journal-ISO	Z.Naturforsch.(B)
Doc-Delivery-Number	451KA